PTHH: \(2CuS+3O_2\xrightarrow[]{t^o}2CuO+2SO_2\uparrow\)
a____________a_______a (mol)
\(4FeS+7O_2\xrightarrow[]{t^o}2Fe_2O_3+4SO_2\)
2b_____________b_______2b (mol)
Ta lập hệ phương trình: \(\left\{{}\begin{matrix}96a+88\cdot2b=22,8\\a+2b=\dfrac{5,6}{22,4}=0,25\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,075\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CuO}=\dfrac{0,1\cdot80}{0,1\cdot80+0,075\cdot160}\cdot100\%=40\%\\\%m_{Fe_2O_3}=60\%\end{matrix}\right.\)
a, \(n_{SO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PTHH: CuS + O2 ---to--> CuO + SO2
Mol: x x
PTHH: FeS + O2 ---to→ FeO + SO2
Mol: 0,25-x 0,25-x
Ta có: mFeS + mCuS = 22,8
⇔ (0,25-x).88 + x.96 = 22,8
⇔ 22-88x+96x=22,8
⇔ 8x=0,8
⇔ x=0,1
PTHH: CuS + O2 ---to--> CuO + SO2
Mol: 0,1 0,1 0,1
PTHH: FeS + O2 ---to→ FeO + SO2
Mol: 0,15 0,15 0,15
mhh = 0,1.96+0,15.88=22,8 (g)
⇒ \(\%m_{FeO}=\dfrac{0,15.88.100\%}{22,8}=57,9\%;\%m_{CuO}=\dfrac{0,1.96.100\%}{22,8}=42,1\%\)