Fe2O3 + 6HCl \(\rightarrow\)2FeCl3 + 3H2O (1)
MgO + 2HCl \(\rightarrow\)MgCl2 + H2O (2)
Ca(OH)2 + 2HCl \(\rightarrow\)CaCl2 + 2H2O (3)
nCa(OH)2=\(\dfrac{50.14,8\%}{74}=0,1\left(mol\right)\)
Theo PTHH 3 ta có:
nCa(OH)2=nCaCl2=0,1(mol)
2nCa(OH)2=nHCl=0,2(mol)
mCaCl2=111.0,1=11,1(g)
mmuối của Mg,Fe=46,35-11,1=35,25(g)
Đặt nFe2O3=a
nMgO=b
Ta có:
\(\left\{{}\begin{matrix}160a+40b=16\\325a+95b=35,25\end{matrix}\right.\)
=>a=0,05;b=0,2
mFe2O3=160.0,05=8(g)
%mFe2O3=\(\dfrac{8}{16}.100\%=50\%\)
%mMgO=100-50=50%
Từ 1 ta có:
6nFe2O3=nHCl(1)=0,3(mol)
2nMgO=nHCl=0,2(mol)
=>\(\sum\)nHCl=0,3+0,2+0,2=0,7(mol)
CM dd HCl=\(\dfrac{0,7}{0,3}=\dfrac{7}{3}M\)