a) PTPỨ: \(SO_2+NaOH\rightarrow NaHSO_3\)
\(SO_2+2NaOH\rightarrow Na_2SO_3+H_2O\)
b) \(n_{SO_2}=0,2\left(mol\right);n_{NaOH}=1.0,25=0,25\left(mol\right)\)
\(\Rightarrow\frac{n_{NaOH}}{n_{SO_2}}=\frac{0,25}{0,2}=1,25\)
\(SO_2+NaOH\rightarrow NaHSO_3\)
a a a
\(SO_2+2NaOH\rightarrow Na_2SO_3+H_2O\)
b 2b b
\(\Rightarrow\left\{{}\begin{matrix}a+b=0,2\\a+2b=0,25\end{matrix}\right.\)
Giải ra ta được: \(a=0,15mol;b=0,05mol\)
\(\rightarrow m_{Na_2SO_3}=0,05\left(23,2+32+48\right)=6,3\left(g\right)\)
\(\rightarrow m_{NaHSO_3}=0,15\left(23+1+32+48\right)=15,6\left(g\right)\)
