Bài 1.
\(n_{H^+}=2n_{H_2SO_4}=2.10^{-2}.0,1=0,002\) mol
\(n_{OH^-}=n_{NaOH}=0,01.0,1=0,001\) mol
\(H^++OH^-\rightarrow H_2O\)
0,001<-0,001
\(\Rightarrow n_{H^+}\text{còn}=0,002-0,001=0,001\) mol
\(\Rightarrow\left[H^+\right]=\dfrac{0,001}{0,2}=0,005\) mol/lít
\(\Rightarrow pH=-lg\left[H^+\right]=-lg\left(\dfrac{0,001}{0,2}\right)=2,3\)
\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)
0,0005<--0,001------> 0,001
\(Na_2SO_4\rightarrow2Na^++SO_4^{2-}\)
0,001 ------>0,002-->0,001
\(H_2SO_4\rightarrow2H^++SO_4^{2-}\)
0,0005--->0,001-->0,0005
\(\Rightarrow\left[Na^+\right]=\dfrac{0,002}{0,2}=0,01\) mol/lít; \(\left[SO_4^{2-}\right]=\dfrac{0,001+0,0005}{0,2}=0,0075\) mol/lít
\(\left[H^+\right]=0,005\) mol/lít