a)\(n_{CaSO_3\downarrow}=0,95\left(mol\right)\)
Bảo toàn ntố S: \(n_{SO2}=n_{CaSo_3}=0,95\left(mol\right)\)
Đặt \(\left\{{}\begin{matrix}n_{Fe}=x\\n_{Mg}=y\end{matrix}\right.\)\(\Rightarrow56x+24y=28,8\)(1)
Bảo toàn electron: \(3x+2y=2.n_{SO_2}=1,9\)
\(\Rightarrow\left\{{}\begin{matrix}56x+24y=28,8\\3x+2y=1,9\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,3\\y=0,5\end{matrix}\right.\)
\(\Rightarrow\%Fe=\dfrac{56.0,3}{28,8}.100\%=58,3\%\)\(\Rightarrow\%Mg=41,7\%\)
b) Bảo toàn Mg: \(n_{Mg}=n_{MgSO_4}=0,5\left(mol\right)\) ; Bảo toàn Fe: \(n_{Fe_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Fe}=0,15\left(mol\right)\)
Bảo toàn S : \(n_{H_2SO_4}=n_{MgSO_4}+3n_{Fe_2\left(SO_4\right)_3}+n_{SO_2}=1,9\left(mol\right)\)
\(\Rightarrow C\%H_2SO_4=\dfrac{1,9.98}{285}.100\%=65,3\%\)
\(m_{dd}=m_{Kl}+m_{ddH_2SO_4}-m_{SO_2}=28,8+285-0,95.64=253\left(g\right)\)
(sau p/u)
\(\Rightarrow C\%_{MgSO_4}=\dfrac{0,5.120}{253}.100\%=23,71\%\)
\(C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0,15.400}{253}.100\%=23,71\%\)