a) Ta có: 2Na + 1C + 3X = CaCO3 + 3H2
\(\Rightarrow\left(2\times23\right)+\left(1\times12\right)+3X=100+\left(3\times2\right)\)
\(\Rightarrow46+12+3X=106\)
\(\Rightarrow X=\dfrac{106-\left(46+12\right)}{3}=16\) (đvC)
Vậy X là nguyên tố Oxi (O)
b) Ta có: 2Al + 3X + 12O = 19 \(\times\) H2O
\(\Rightarrow\left(2\times27\right)+3X+\left(12\times16\right)=19\times18\)
\(\Rightarrow54+3X+192=342\)
\(\Rightarrow X=\dfrac{342-\left(54+192\right)}{3}=32\) (đvC)
Vậy X là nguyên tố Lưu huỳnh (S).