Question

Trộn lẫn 100ml dd NaOH 0,03M với 10ml dd HNO3 0,01M thu được dd Y. Tính pH của dd Y

Answer 1

\(n_{NaOH}=0,03.0,1=0,003\left(mol\right)\\ n_{HNO_3}=0,01.0,01=0,0001\left(mol\right)\\ NaOH+HNO_3\rightarrow NaNO_3+H_2O\\ Vì:\dfrac{0,0001}{1}< \dfrac{0,003}{1}\\ \Rightarrow NaOHdư\\ n_{NaOH\left(dư\right)}=0,003-0,0001=0,0029\left(mol\right)\\ \left[OH^-\left(dư\right)\right]=\left[NaOH_{dư}\right]=\dfrac{0,0029}{0,01+0,1}=\dfrac{29}{1100}\left(M\right)\\ \Rightarrow pH=14+log\left[\dfrac{29}{1100}\right]\approx12,421\)