\(\text{Na2CO3 + 2HCl -> 2NaCl + CO2 + H2O}\)
Ta có:
\(\text{ nNa2CO3=21,2/106=0,2 mol}\)
mHCl=200.3,4%=6,8 gam -> nHCl=6,8/73=34/365
Ta có: nHCl < 2Na2CO3 nên Na2CO3 dư
-> nCO2=1/2nHCl=17/365 mol -> V CO2 =17/365 .22,4=1,04 lít
b)
BTKL: m dung dịch sau phản ứng=21,2+200- m CO2=21,2+200-17/365.44=219,15 gam
Sau phản ứng dung dịch thu được chứa NaCl 34/365 mol và Na2CO3 dư 0,2-17/365=56/365
\(\text{-> m NaCl=34/365 .58=5,4 gam}\)
\(\text{-> mNa2CO3 dư=56/365.106=16,26 ga}\)\(-\text{>% NaCl=2,46 %; %Na2CO3=7,42 %}\)
Na2CO3+2HCl---->2NaCl+H2O+CO2
a)n Na2CO3=\(\frac{21,2}{106}=0,2\left(mol\right)\)
n HCl=\(\frac{200.3,4}{100.36,5}=0,186\left(mol\right)\)
-----> Na2CO3 dư
Theo pthh
n CO2=1/2 n HCl=0,093(mol)---> mCO2=0,093.44=4,092(g)
V CO2= 0,093.22,4=2,0832(l)
b) m dd sau pư=21,2+200-4,092=217,108(g)
n Na2CO3 dư=0,2-0,093=0,107(mol)
C% Na2CO3 dư=\(\frac{0,107.106}{217,108}.100\%=5,22\%\)
n NaCl=n HCl=0,186(mol)
C% NaCl=\(\frac{0,186.58,5}{217,108}.100\%=5.012\%\)