a) CaO + 2HCl --> CaCl2 + H2O
CaCO3 + 2HCl --> CaCl2 + CO2 + H2O
b) \(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PTHH: CaCO3 + 2HCl --> CaCl2 + CO2 + H2O
_____0,1<-----0,2<-------0,1<-----0,1
=> mCaCO3 = 0,1.100 = 10 (g)
=> mCaO = 15,6 - 10 = 5,6 (g)
b) \(n_{CaO}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
PTHH:CaO + 2HCl --> CaCl2 + H2O
_____0,1--->0,2------>0,1
=> mHCl = (0,2+0,2).36,5 = 14,6 (g)
=> \(m_{ddHCl}=\dfrac{14,6.100}{14,6}=100\left(g\right)\)
mdd sau pư = 15,6 + 100 - 0,1.44 = 111,2 (g)
=> \(C\%\left(CaCl_2\right)=\dfrac{\left(0,1+0,1\right).111}{111,2}.100\%=19,96\%\)
PTHH : CaO + 2HCl ---> CaCl2 + H2O (1)
1 : 2 : 1 : 2
CaCO3 + 2HCl ---> CaCl2 + H2O + CO2 (2)
1 : 2 : 1 : 1 : 1
Ta có \(n_{CO_2}=\dfrac{V}{22.4}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
=> \(n_{CaCO_3}=0,1\left(mol\right)\)
=> \(m_{CaCO_3}=n.M=0,1.100=10\left(g\right)\)
=> mCaO = 15,6 - 10 = 5,6 (g)
c) \(n_{CaO}=\dfrac{m}{M}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
\(m_{CO_2}=n.M=0,1.44=4,4\left(g\right)\)
Ta có \(m_{HCl}=m_{HCl\left(1\right)}+m_{HCl\left(2\right)}\)
\(=n_{HCl\left(1\right)}.M+n_{HCl\left(2\right)}.M\)
\(0,2.36,5+0,2.36,5=14,6\left(g\right)\)
=> \(m_{ddHCl}=\dfrac{m_{HCl}.100\%}{C\%}=\dfrac{14,6.100\%}{14.6\%}100\left(g\right)\)
\(m_{dd\text{ sau pư}}=m_{ddHCl}+m_{CaO}+m_{CaCO_3}-m_{CO_2}\)
= 100 + 5.6 + 10 - 4,4 = 111.2(g)
=> \(m_{CaCl_2}=m_{CaCl_2\left(1\right)}+m_{CaCl_2\left(2\right)}\)
\(=n_{CaCl_2\left(1\right)}.M+n_{CaCl_2\left(2\right)}.M\)
= 0,1.91 + 0,1.91 = 18,2 (g)
=> \(C\%=\dfrac{m_{CaCl_2}}{m_{\text{dd sau pư}}}.100\%=\dfrac{18,2}{111,2}.100\%=16,37\%\)
