a,\(\text{ nNaOH=0,35.0,5=0,175 mol}\)
nCO2=\(\frac{5,6}{22,4}\)=0,25 mol
\(\frac{nOH^-}{nCO2}\)=\(\frac{0,175}{0,25}\)=0,7
\(\rightarrow\) Spu chỉ thu đc NaH2PO4, dư CO2
\(\rightarrow\) \(\text{nNaH2PO4=nNaOH=0,175 mol}\)
\(\rightarrow\)CM NaH2PO4=\(\frac{0,175}{0,5}\)=0,35M
b,
\(\text{NaH2PO4+2NaOH=Na3PO4+2H2O}\)
\(\rightarrow\) \(\text{nNaOH=2nNaH2PO4=0,35 mol}\)
\(\rightarrow\) V NaOH=\(\frac{0,35}{0,5}\)=0,7l= 700ml