PTHH:
\(FeO+H_2\underrightarrow{t^o}Fe+H_2O\left(1\right)\)
a a a a
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\left(2\right)\)
b 3b 2b 3b
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\left(3\right)\)
100(ml)=0,1(l)
\(n_{H_2SO_4}=0,1.2=0,2\left(mol\right)\)
Theo (3): \(n_{Fe}=n_{H_2SO_4}=0,2\left(mol\right)\)
\(m_{Fe}=0,2.56=11,2\left(g\right)\)
Gọi nFeO là a, số mol Fe2O3 là b, ta có:
\(\left\{{}\begin{matrix}56a+56.2b=11,2\\72a+160b=15,2\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}a=0,1\\b=0,05\end{matrix}\right.\)
\(\%FeO=\dfrac{m_{FeO}}{m_{hh}}=\dfrac{0,1.72}{15,2}=47,37\%\)
\(\%Fe_2O_3=100\%-47,37\%=52,63\%\)
b) Theo (1) và (2)
\(\sum V_{H_2}=\sum n_{H_2}.22,4=\left(a+3b\right).22,4=\left(0,1+0,05.3\right),22,4=5,6\left(l\right)\)
c) Theo (3): \(n_{FeSO_4.7H_2O}=n_{FeSO_4}=n_{Fe}=0,2\left(mol\right)\)
\(m_{FeSO_4.7H_2O}=0,2.278=55,6\left(g\right)\)
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