Xét cho hợp lí thì cách giải như vậy không hoàn hảo. Nhưng không thể làm khác được và đề không hề sai.
\(2CH_3COOH\left(\dfrac{1}{3}\right)+Zn--->\left(CH_3COO\right)_2Zn+H_2\left(\dfrac{1}{6}\right)\)\(\left(1\right)\)
\(m_{CH_3COOH}=\dfrac{10.200}{100}=20\left(g\right)\)
\(\Rightarrow n_{CH_3COOH}=\dfrac{1}{3}\left(mol\right)\)
\(Theo\left(1\right):n_{H_2}=\dfrac{1}{6}\left(mol\right)\)
\(\Rightarrow V_{H_2}\left(đktc\right)=3,73\left(l\right)\)
\(C_2H_5OH\left(\dfrac{1}{6}\right)+O_2-t^o->CH_3COOH\left(\dfrac{1}{6}\right)+H_2O\)\(\left(2\right)\)
\(Theo\left(2\right):n_{C_2H_5OH}\left(lt\right)=\dfrac{1}{6}\left(mol\right)\)
Vì \(H=80\%\)
\(\Rightarrow n_{C_2H_5OH}\left(tt\right)=\dfrac{5}{24}\left(mol\right)\)
\(\Rightarrow m_{C_2H_5OH}=13,33\left(g\right)\)
\(\Rightarrow V_{C_2H_5OH}=\dfrac{13,33}{0,8}=16,6625\left(l\right)\)
\(\Rightarrow V_{ddC_2H_5OH}\left(15^o\right)=\dfrac{16,6625.100}{15}=111,08\left(l\right)\)
