nAl = 0.81/27 = 0.03 mol
nS = 0.8/32 = 0.025 mol
2Al + 3S -to-> Al2S3
Bđ: 0.03__0.025
Pư: 1/60__0.025____1/120
Kt: 1/75___0_______1/120
2Al + 6HCl --> 2AlCl3 + 3H2
1/75__________________0.02
Al2S3 + 6HCl --> 2AlCl3 + 3H2S
1/120___________________0.025
V = ( 0.02 + 0.025 ) *22.4 = 1.008 (l)
mH2S = 0.85 g
mdd NaOH = 25*1.28 = 32 g
mNaOH = 32*15/100=4.8 g
nNaOH = 4.8/40 = 0.12 mol
nNaOH/nH2S = 0.12/0.025=4.8 > 2
=> Tạo ra muối Na2S, NaOH dư
2NaOH + H2S --> Na2S + 2H2O
0.05_____0.025___0.025
mdd sau phản ứng = 0.85 + 32 = 32.85 g
mNa2S = 1.95 g
mNaOH dư = 2.8 g
C%Na2S = 5.93%
C%NaOH = 8.52%