a) Fe2O3 + 6HCl \(\rightarrow\) 2FeCl3 + 3H2O
----0,02------0,12-------0,04------0,06 (mol)
nFe2O3 = \(\dfrac{m}{M}=\dfrac{3,2}{160}=0,02\) (mol)
mHCl = n . M = 0,12 . 36,5 = 4,38 (g)
C%HCl = \(\dfrac{m.100}{m_{dd}}=\dfrac{4,38.100}{200}=\) 2,19%
b) Fe2O3 + 6HCl \(\rightarrow\) 2FeCl3 + 3H2O
TPỨ:0,02---0,137
PỨ: 0,02-----0,02
SPỨ: 0------0,117------0,04------0,06
mHCl = \(\dfrac{C\%.m_{dd}}{100}=\dfrac{2,5.200}{100}=5\) (g)
nHCl = \(\dfrac{m}{M}=\dfrac{5}{36,5}\approx\) 0,137 (mol)
So sánh: \(\dfrac{0,02}{1}< \dfrac{0,137}{6}\)
\(\Rightarrow\) HCl dư
Mdd SPỨ = 3,2 + 200 = 203,2 (g)
mFeCl3 = n . M = 0,04 . 162,5 = 6,5 (g)
C%FeCl3 = \(\dfrac{m.100}{m_{dd}}=\dfrac{6,5.100}{203,2}\approx\) 3,2%
Có gì sai thì bạn thông cảm nha ;p