a. mdd X= 6,2+193,8= 200(g)=> C%X=\(\dfrac{6,2\cdot100}{200}=3,1\%\)
b. 2NaOH + CuSO4 ---> Na2SO4 + Cu(OH)2;
0,155--------0,0775------------0,0775----------0,0775 (mol)
Ta có: nCuSO4=\(\dfrac{200\cdot16}{100\cdot160}=0,2\left(mol\right)\)
nNaOH=\(\dfrac{6,2}{40}0,155\left(mol\right)\)
Xét tỉ lệ:\(\dfrac{nNaOH}{nNaOHpt}=\dfrac{0,155}{2}< \dfrac{nCuSO4}{nCuSO4pt}=\dfrac{0,2}{1}\)
=> CuSO4 dư. Sản phẩm tính theo NaOH.
=> nNa2SO4=0,155/2= 0,0775(mol)=> mNa2SO4=0,0775*142=11,005(g).
nCu(OH)2=0,155/2=0,0775(mol)=> mCu(OH)2=0,0775*98=7,595(g).
=> mdd sau pư= 200+200-7,595=392,405(g)
=> C%ddA=\(\dfrac{11,005\cdot100}{392,405}=2,8\%\)
c. Cu(OH)2 ---to-> CuO + H2O;
ta có: nCu(OH)2=0,0775(mol)=> nCuO=0,0775(mol)
CuO + 2 HCl --> CuCl2 + H2O;
0,0775---0,155 (mol)
nHCl=0,155(mol)=>mHCl=0,155*36,5=5,6575(g)