Coi X là kim loại R có hóa trị n
\(2R + 2nHCl \to 2RCl_n + nH_2\)
Theo PTHH : \(n_R = \dfrac{2}{n}.n_{H_2} = \dfrac{0,3}{n}(mol)\)
\(n_{AgNO_3} = 0,14(mol) ; n_{Cu(NO_3)_2} = 0,1(mol)\)
\(R + nAgNO_3 \to R(NO_3)_n + nAg\\ \)
\(\dfrac{0,14}{n}\).....\(0,14\)............................\(0,14\).................(mol)
\(2R + nCu(NO_3)_2 \to 2R(NO_3)_n + nCu\)
\(\dfrac{0,2}{n}\)......0,1.....................................0.1.............(mol)
Vì \(\dfrac{0,14}{n}\) + \(\dfrac{0,2}{n}\) < \(\dfrac{0,3}{n}\) nên Cu(NO3)2 dư
\(2R + nCu(NO_3)_2 \to 2R(NO_3)_n + nCu\)
\(\dfrac{0,16}{n}\)........0,08....................................0,08...........(mol)
Suy ra : a = 0,14.108 + 0,08.64 = 20,24(gam)