Đặt nK2CO3 là x mol và nKHCO3 là y mol
mHCl = 4,675 gam
nHCL = 0,128 mol
nCO2 = 0,1 mol
K2CO3 (x) + 2HCl (2x) ------> 2KCl (2x) + CO2 (x) + H2O (1)
KHCO3 (y) + HCl (y) ------> KCl (y) + CO2 (y) + H2O (2)
- Theo PTHH(1,2): \(\Rightarrow\left\{{}\begin{matrix}2x+y=0,128\left(I\right)\\x+y=0,1\left(II\right)\end{matrix}\right.\)
-Giải hệ PT(I,II): \(\Rightarrow\left\{{}\begin{matrix}x=0,028mol\\y=0,072mol\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}mK2CO3=3,864gam\\mKHCO3=7,2gam\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%mK2CO3=\dfrac{3,864.100\%}{3,864+7,2}=53,67\%\\\%mKHCO3=100\%-53,67\%=46,33\%\end{matrix}\right.\)
- Theo PTHH(1,2): nKCl = 0,128mol
=> mKCl = 9,536 gam