a)
Mg+2AgNO3\(\rightarrow\)Mg(NO3)2+2Ag
Mg+Cu(NO3)2\(\rightarrow\)Mg(NO3)2+Cu
Mg(NO3)2+2NaOH\(\rightarrow\)Mg(OH)2+2NaNO3
Cu(NO3)2+2NaOH\(\rightarrow\)Cu(OH)2+2NaNO3
b)
nMg=\(\frac{3,6}{24}\)=0,15(mol)
nMg(OH)2=nMg(NO3)2=nMg=0,15(mol)
mMg(OH)2=8,7g<13,6
\(\rightarrow\) Có Cu(NO3)2 dư
mCu(OH)2=13,6-8,7=4,9(g)
nCu(OH)2=\(\frac{4,9}{98}\)=0,05(mol)
\(\rightarrow\)nCu(NO3)2 dư=0,05(mol)
Gọi a là số mol AgNO3 b là số mol Cu(NO3)2 trong dd ban đầu
ta có
108a+(b-0,05).64=17,2
\(\frac{a}{2}\)+b-0,05=0,15\(\rightarrow\)\(\frac{a}{2}\)+b=0,2
\(\Rightarrow\left\{{}\begin{matrix}a=0,1\\b=0,15\end{matrix}\right.\)
CMAgNO3=\(\frac{0,1}{0,5}\)=0,2(M)
CMCu(NO3)2=\(\frac{0,15}{0,5}\)=0,3(M)