PTHH: \(Na_2CO_3+2CH_3COOH\rightarrow2CH_3COONa+H_2O+CO_2\uparrow\)
Tính theo sản phẩm
Ta có: \(\left\{{}\begin{matrix}\Sigma n_{CH_3COOH}=\dfrac{160\cdot15\%}{60}=0,4\left(mol\right)\\n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_3COOH\left(dư\right)}=0,2\left(mol\right)=n_{CH_3COONa}\\n_{Na_2CO_3}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Na_2CO_3}=0,1\cdot106=10,6\left(g\right)\\m_{CH_3COONa}=0,2\cdot82=16,4\left(g\right)\\m_{CH_3COOH\left(dư\right)}=0,2\cdot60=12\left(g\right)\\m_{CO_2}=0,1\cdot44=4,4\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(sau.p/ứ\right)}=m_{Na_2CO_3}+m_{ddAxit}-m_{CO_2}=166,2\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{CH_3COONa}=\dfrac{16,4}{166,2}\cdot100\%\approx9,87\%\\C\%_{CH_3COOH\left(dư\right)}=\dfrac{12}{166,2}\cdot100\%\approx7,22\%\end{matrix}\right.\)
Ta có: \(\left\{{}\begin{matrix}n_{CO_2}=0,1\left(mol\right)\\n_{NaOH}=0,5\cdot0,3=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Tạo 2 muối
PTHH: \(CO_2+NaOH\rightarrow NaHCO_3\)
a_______a__________a (mol)
\(CO_2+2NaOH\rightarrow Na_2CO_3+H_2O\)
b_______2b_________2b (mol)
Ta lập được HPT \(\left\{{}\begin{matrix}a+b=0,1\\a+2b=0,15\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,05\\b=0,05\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{NaHCO_3}=0,05\cdot84=4,2\left(g\right)\\m_{Na_2CO_3}=0,05\cdot106=5,3\left(g\right)\end{matrix}\right.\)