Cho luồng khí CO đi qua ống đựng 16g dung dịch Fe2O3 ở nhiệt độ cao .Sau một thời gian thu được m(g) hỗn hợp chất rắn A gồm Fe, Fe2O3, Fe3O4, FeO và một chất khí X. Cho chất khí X tác dụng với nước vôi trong thu được 6g kết tủa. Cho m(g) chất rắn A tác dụng với axit H2SO4 đặc nóng thu được V(l) khí SO2 duy nhất là bao nhiều ?,......bài này có thể quy đổi hh A thành ( Fe, FeO) được không ạ? Nếu dc thì giải luôn cách đó giùm e ạ....thanks
nCO2 =nCa(OH)2=6/100=0,06 mol=nCO pứ
nFe2O3=16/160=0,1 mol
=>nFe=0,2 mol
bảo toàn Fe nFe hh sau pứ=0,2 mol
bảo toàn klg=> m cr sau pứ=16+0,06.28-0,06.44=15,04 gam
GS hh cr sau pứ gồm Fe và O
=>mO=15,04-0,2.56=3,84 gam
=>nO=0,24 mol
khi cho hh cr tác dụng với H2SO4 đặc nóng
O +2e => O−2
0,24 mol=>0,48 mol
S+6 +2e => S+4
0,12 mol=>0,06 mol
Fe => Fe+3 +3e
0,2 mol =>0,6 mol
VSO2=0,06.22,4=1,344 lit
c giải cho e r mà?
nCO2=nCa(OH)2=6/100=0,06 mol=nCO
nFe2O3=16/160=0,1 mol=>nFe=0,2 mol
bảo toàn ngtố Fe nFe hh sau pứ=0,2 mol
bảo toàn klg=> m cr sau pứ=16+0,06.28-0,06.44=15,04 gam
GS hh cr sau pứ gồm Fe và O
=>mO=15,04-0,2.56=3,84 gam
=>nO=0,24 mol
khi cho hh cr tác dụng với H2SO4 đặc nóng
O +2e => O-20,24 mol=>0,48 mol
S+6 +2e => S+4
0,12 mol=>0,06 mol
Fe => Fe+3 +3e
0,2 mol =>0,6 mol
VSO2=0,06.22,4=1,344 lit
(lỗi kí tự hóa học)
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O" role="presentation" style="background:transparent; border:0px; color:rgb(0, 0, 0); direction:ltr; display:inline; float:none; font-family:arial,liberation sans,dejavu sans,sans-serif; font-size:13.696px; line-height:normal; margin:0px; max-height:none; max-width:none; min-height:0px; min-width:0px; padding:0px; position:relative; vertical-align:baseline; white-space:nowrap; word-wrap:normal" class="MathJax">OO" role="presentation" style="background:transparent; border:0px; color:rgb(0, 0, 0); direction:ltr; display:inline; float:none; font-family:arial,liberation sans,dejavu sans,sans-serif; font-size:13.696px; line-height:normal; margin:0px; max-height:none; max-width:none; min-height:0px; min-width:0px; padding:0px; position:relative; vertical-align:baseline; white-space:nowrap; word-wrap:normal" class="MathJax">OH2SO4" role="presentation" style="background:transparent; border:0px; color:rgb(0, 0, 0); direction:ltr; display:inline; float:none; font-family:arial,liberation sans,dejavu sans,sans-serif; font-size:13.696px; line-height:normal; margin:0px; max-height:none; max-width:none; min-height:0px; min-width:0px; padding:0px; position:relative; vertical-align:baseline; white-space:nowrap; word-wrap:normal" class="MathJax">H2SO4O" role="presentation" style="background:transparent; border:0px; color:rgb(0, 0, 0); direction:ltr; display:inline; float:none; font-family:arial,liberation sans,dejavu sans,sans-serif; font-size:13.696px; line-height:normal; margin:0px; max-height:none; max-width:none; min-height:0px; min-width:0px; padding:0px; position:relative; vertical-align:baseline; white-space:nowrap; word-wrap:normal" class="MathJax">OO−2" role="presentation" style="background:transparent; border:0px; color:rgb(0, 0, 0); direction:ltr; display:inline; float:none; font-family:arial,liberation sans,dejavu sans,sans-serif; font-size:13.696px; line-height:normal; margin:0px; max-height:none; max-width:none; min-height:0px; min-width:0px; padding:0px; position:relative; vertical-align:baseline; white-space:nowrap; word-wrap:normal" class="MathJax">O−2
S+6" role="presentation" style="background:transparent; border:0px; color:rgb(0, 0, 0); direction:ltr; display:inline; float:none; font-family:arial,liberation sans,dejavu sans,sans-serif; font-size:13.696px; line-height:normal; margin:0px; max-height:none; max-width:none; min-height:0px; min-width:0px; padding:0px; position:relative; vertical-align:baseline; white-space:nowrap; word-wrap:normal" class="MathJax">S+6S+4" role="presentation" style="background:transparent; border:0px; color:rgb(0, 0, 0); direction:ltr; display:inline; float:none; font-family:arial,liberation sans,dejavu sans,sans-serif; font-size:13.696px; line-height:normal; margin:0px; max-height:none; max-width:none; min-height:0px; min-width:0px; padding:0px; position:relative; vertical-align:baseline; white-space:nowrap; word-wrap:normal" class="MathJax">S+4
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