\(MnO_2+4HCl\rightarrow MnCl_2+Cl_2+H_2O\)
Ta có:
\(n_{MnO2}=\frac{69,2}{55+16.2}=0,8\left(mol\right)\)
Theo phản ứng: \(n_{Cl2}=n_{MnO2}=0,8\left(mol\right)\)
Ta có: \(n_{NaOH}=0,5.4=2\left(mol\right)\)
\(Cl_2+2NaOH\rightarrow NaCl+NaClO+H_2O\)
Vì \(n_{NaOH}>2n_{Cl2}\Rightarrow\) NaOH dư
\(n_{NaCl}=n_{NaClO}=n_{Cl2}=0,8\left(mol\right)\)
\(n_{NaOH_{Dư}}=2-0,8.2=0,4\left(mol\right)\)
V dung dịch = 500ml = 0,5 lít
\(CM_{NaCl}=CM_{NaClO}=\frac{0,8}{0,5}=1,6M\)
\(CM_{NaOH_{Dư}}=\frac{0,4}{0,5}=0,8M\)