2Al + 6HCl \(\rightarrow\) 2AlCl3 + 3H2 (1)
Mg + 2HCl \(\rightarrow\) MgCl2 + H2 (2)
nH2 = V/22,4 = 6,72/22,4 = 0,3(mol)
Đặt \(\left\{{}\begin{matrix}n_{Al}=a\left(mol\right)\\n_{Mg}=b\left(mol\right)\end{matrix}\right.\) => mAl = 27a(g) và mMg = 24b(g)
mà mAl + mMg = 6,4(g)
=> 27a + 24b = 6,4
Theo PT(1) => nH2 = 3/2 . nAl = 3/2 .a(mol)
Theo PT(2) => nH2 = nMg = b (mol)
mà tổng nH2 = 0,3(mol)
=> 3/2.a + b = 0,3
Do đó : \(\left\{{}\begin{matrix}27a+24b=6,3\\\dfrac{3}{2}a+b=0,3\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,15\left(mol\right)\end{matrix}\right.\)
=> mAl = 27a = 0,1 x 27 = 2,7(g)
=> mMg = 6,3 - 2,7 =3,6(g)
nH2=\(\dfrac{V}{22,4}\)=\(\dfrac{6,72}{22,4}=0,3\) mol
PTHH(1): 2Al + 6HCl ------> 2AlCl3 + 3H2
nAl=\(\dfrac{0,3.2}{3}=0,2mol\)
mAl=n.M=0,2.27=5,4g
PTHH(2): Mg + 2HCl ------> MgCl2 + H2
nMg=\(\dfrac{0,3.1}{1}=0,3mol\)
mMg=n.M=0,3.24=7,2g