a) PTHH: H2SO4 + BaCl2 ➜ BaSO4↓ + 2HCl
b) \(m_{H_2SO_4}=49\times20\%=9,8\left(g\right)\)
\(\Rightarrow n_{H_2SO_4}=\dfrac{9,8}{98}=0,1\left(mol\right)\)
\(m_{BaCl_2}=200\times5,2\%=10,4\left(g\right)\)
\(\Rightarrow n_{BaCl_2}=\dfrac{10,4}{208}=0,05\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{BaCl_2}\)
Theo bài: \(n_{H_2SO_4}=2n_{BaCl_2}\)
Vì \(2>1\) ⇒ dd H2SO4 dư, dd BaCl2 hết
Kết tủa A gồm: BaSO4
Theo PT: \(n_{BaSO_4}=n_{BaCl_2}=0,05\left(mol\right)\)
\(\Rightarrow m_{BaSO_4}=0,05\times233=11,65\left(g\right)\)
c) Dung dịch B gồm: HCl, H2SO4 dư
Theo PT: \(n_{H_2SO_4}pư=n_{BaCl_2}=0,05\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4}dư=0,1-0,05=0,05\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}dư=0,05\times98=4,9\left(g\right)\)
Theo PT: \(n_{HCl}=2n_{BaCl_2}=2\times0,05=0,1\left(mol\right)\)
\(\Rightarrow m_{HCl}=0,1\times36,5=3,65\left(g\right)\)
\(\Sigma m_{ddB}=49+200=249\left(g\right)\)
\(C\%_{ddH_2SO_4}dư=\dfrac{4,9}{249}\times100\%\approx1,97\%\)
\(C\%_{ddHCl}=\dfrac{3,65}{249}\times100\%\approx1,47\%\)
