PTHH: \(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\uparrow\)
\(2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\downarrow\)
\(Cu\left(OH\right)_2\xrightarrow[]{t^o}CuO+H_2O\)
\(CuO+H_2\xrightarrow[]{t^o}Cu+H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{Na}=n_{NaOH}=\dfrac{4,6}{23}=0,2\left(mol\right)\Rightarrow n_{H_2}=0,1\left(mol\right)\\n_{CuSO_4}=0,2\cdot1=0,2\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,2}{1}\) \(\Rightarrow\) CuSO4 còn dư, NaOH p/ứ hết
\(\Rightarrow n_{CuO}=0,1\left(mol\right)\) \(\Rightarrow\) Cả CuO và H2 p/ứ hết
\(\Rightarrow n_{Cu}=0,1\left(mol\right)\) \(\Rightarrow m_{Cu}=0,1\cdot64=6,4\left(g\right)\)