$a\big)2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2$
$b\big)$
$n_{Al}=\dfrac{4,05}{27}=0,15(mol)$
$n_{H_2SO_4}=\dfrac{29,4}{98}=0,3(mol)$
Vì $\dfrac{n_{Al}}{2}<\frac{n_{H_2SO_4}}{3}\to H_2SO_4$ dư
$c\big)$
Theo PT: $n_{H_2}=\dfrac{3}{2}n_{Al}=0,225(mol)$
$\to V_{H_2}=0,225.22,4=5,04(l)$