\(m_{KL\left(mỗi.phần\right)}=\dfrac{1}{2}.15,6=7,8\left(g\right)\)
- Phần 1:
\(n_{SO_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)
PTHH:
\(Zn+2H_2SO_{4\left(đ,nóng\right)}\rightarrow ZnSO_4+SO_2\uparrow+2H_2O\left(1\right)\\ Cu+2H_2SO_{4\left(đ,nóng\right)}\rightarrow CuSO_4+SO_2\uparrow+2H_2O\left(2\right)\\ 2Al+6H_2SO_{4\left(đ,nóng\right)}\rightarrow Al_2\left(SO_4\right)_3+3SO_2\uparrow+6H_2O\left(3\right)\)
Theo PTHH (1,2, 3): \(n_{H_2O}=n_{H_2SO_4}=2n_{SO_2}=2.0,35=0,7\left(mol\right)\)
Áp dụng ĐLBTKL:
\(m_{KL}+m_{H_2SO_4}=m_{muối.sunfat}+m_{SO_2}+m_{H_2O}\)
=> mmuối sunfat = 7,8 + 0,7.98 - 0,35.64 - 0,7.18 = 41,4 (g)
\(\rightarrow m_{SO_4^{2-}}=41,4-7,8=33,6\left(g\right)\\ n_{SO_4^{2-}}=\dfrac{33,6}{96}=0,35\left(mol\right)\)
- Phần 2:
PTHH:
\(2Zn+O_2\underrightarrow{t^o}2ZnO\\ 2Cu+O_2\underrightarrow{t^o}2CuO\\ 4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
\(n_{O^{2-}}=n_{SO_4^{2-}}=0,35\left(mol\right)\\ \rightarrow m_{O^{2-}}=0,35.16=5,6\left(g\right)\\ \rightarrow m=5,6+7,8=13,4\left(g\right)\)