Phản ứng xảy ra:
\(MnO_2+4HCl\rightarrow MnCl_2+Cl_2+2H_2O\)
Ta có:
\(n_{MnO2}=\frac{13,05}{55+16.2}=0,15\left(mol\right)\)
\(\Rightarrow n_{Cl2}=n_{MnO2}=0,15\left(mol\right)\)
\(2NaOH+Cl_2\rightarrow NaCl+NaClO+H_2O\)
Vì \(n_{NaOH}=0,5.1=0,5\left(mol\right)>2nCl_2\)
Nên NaOH dư.
\(\Rightarrow n_{NaCl}=n_{NaClO}=n_{Cl2}=0,15\left(mol\right)\)
\(n_{NaOH\left(Dư\right)}=0,5-0,15.2=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}CM_{NaCl}=\frac{0,15}{0,5}=0,3M\\CM_{NaClO}=\frac{0,15}{0,5}=0,3M\\CM_{NaOH\left(dư\right)}=\frac{0,2}{0,5}=0,4M\end{matrix}\right.\)