\(2KMnO_4+16HCl\rightarrow5Cl_2+2KCl+8H_2O\)
\(2NaOH+Cl_2\rightarrow NaCl+NaClO+H_2O\)
\(n_{KMnO4}=\frac{3,16}{158}=0,02\left(mol\right)\)
\(\rightarrow n_{Cl2}=\frac{5}{2}n_{KMnO4}=0,05\left(mol\right)\)
Ta có :
\(\frac{n_{NaOH}}{2}=0,1>\frac{n_{Cl2}}{1}=0,05\)
Nên NaOH dư ,Cl hết
Dung dịch sau phứng gồm NaCl , NaClO, NaOH dư
\(n_{NaOH_{pu}}=2n_{Cl2}=0,1\left(mol\right)\)
\(\rightarrow n_{NaOH_{du}}=0,2-0,1=0,1\left(mol\right)\)
\(\rightarrow CM_{NaOH}=\frac{0,1}{0,2}=0,5M\)
\(n_{NaCl}=n_{Cl2}=0,05\left(mol\right)\rightarrow CM_{NaCl}=\frac{0,05}{2}=0,025M\)
\(n_{NaClO}=n_{Cl2}=0,05\left(mol\right)\rightarrow CM_{NaClO}=\frac{0,05}{2}=0,025M\)