PTHH: \(FeCl_2+2KOH\rightarrow2KCl+Fe\left(OH\right)_2\downarrow\)
a) Ta có: \(\left\{{}\begin{matrix}n_{FeCl_2}=\dfrac{25,4}{127}=0,2\left(mol\right)\\n_{KOH}=\dfrac{28}{56}=0,5\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,5}{2}\) \(\Rightarrow\) FeCl2 p/ứ hết, KOH dư
\(\Rightarrow n_{Fe\left(OH\right)_2}=0,2\left(mol\right)\) \(\Rightarrow m_{Fe\left(OH\right)_2}=0,2\cdot90=18\left(g\right)\)
b)
+) Nung trong không khí
PTHH: \(4Fe\left(OH\right)_2+O_2\xrightarrow[]{t^o}2Fe_2O_3+4H_2O\)
Theo PTHH: \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_2}=0,1\left(mol\right)\) \(\Rightarrow m_{Fe_2O_3}=0,1\cdot160=16\left(g\right)\)
+) Nung trong chân không
PTHH: \(Fe\left(OH\right)_2\xrightarrow[]{t^o}FeO+H_2O\)
Theo PTHH: \(n_{FeO}=n_{Fe\left(OH\right)_2}=0,2\left(mol\right)\) \(\Rightarrow m_{FeO}=0,2\cdot72=14,4\left(g\right)\)