Đặt :
CM KOH = x M
CM H2SO4 = y M
TN1:
nKOH = 0.3x mol
nH2SO4 = 0.2y mol
nK2SO4 = 0.5*0.1= 0.05 mol
nKOH dư = 0.1*0.3=0.03 mol
nKOH pư = 0.3x - 0.03 mol
2KOH + H2SO4 --> K2SO4 + H2O
0.4y_____0.2y
<=> 0.3x - 0.03 = 0.4y
<=> 0.3x - 0.4y = 0.03 (1)
TN2:
nKOH= 0.2x mol
nH2SO4 = 0.3y mol
nH2SO4 dư = 0.3*0.2=0.06 mol
nH2SO4 pư = 0.3y - 0.06 mol
2KOH + H2SO4 --> K2SO4 + H2O
0.2x______0.1x
<=> 0.1x = 0.3y - 0.06
<=> 0.1x - 0.3y = -0.06 (2)
Giải (1) và (2) :
x=0.66
y=0.42