Gọi \(\left\{{}\begin{matrix}n_{Na2CO3}:x\left(mol\right)\\n_{NaHCO3}:y\left(mol\right)\end{matrix}\right.\)
Thí nghiệm 1:
\(Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O\left(1\right)\)
x_________2x_________________________
\(NaHCO_3+HCl\rightarrow NaCl+CO_2+H_2O\left(2\right)\)
y___________y__________________________
\(HCl+NaOH\rightarrow NaCl+H_2O\left(3\right)\)
Ta có:
\(n_{HCl\left(trong.100ml\right)}=0,1.1=0,1\left(mol\right)\)
\(n_{HCl\left(dư\right)\left(1+2\right)}=0,014.2=0,028\left(mol\right)\)
\(n_{HCl\left(da.dung\right)}=2x+y=0,1-0,028=0,072\left(mol\right)\left(4\right)\)
Thí ngiệm 2:
\(BaCl_2+Na_2CO_3\rightarrow BaCO_3+2NaCl\left(5\right)\)
Sau khi lọc bỏ kết tủa , nước rửa chứa NaHCO3 cho tác dụng với dung dịch HCl
\(NaHCO_3+HCl\rightarrow NaCl+CO_2+H_2O\left(6\right)\)
Theo PTHH 6:
\(y=0,026.1=0,026\left(mol\right)\)
Thay y vào (4) \(x=0,023\left(mol\right)\)
\(CM_{Na2CO3}=\frac{0,023}{0,025}=0,92M\)
\(CM_{NaHCO3}=\frac{0,026}{0,025}=1,04M\)