2Al + 6HCl -> 2AlCl3 + 3 H2 (1)
Fe + 2HCl -> FeCl2 + H2 (2)
nH2=\(\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
nHCl=\(\dfrac{200.14,6\%}{36,5}=0,8\left(mol\right)\)
Đặt nAl=a
nFe=b
Ta có hệ:
\(\left\{{}\begin{matrix}27a+56b=8,3\\1,5a+b=0,25\end{matrix}\right.\)
=>a=b=0,1
Theo PTHH 1 và 2 ta có:
nAl=nAlCl3=0,1(mol)
3nAl=nHCl=0,3(mol)
nFe=nFeCl2=0,1(mol)
2nFe=nHCl=0,2(mol)
nHCl dư=0,8-0,3-0,2=0,3(mol)
mAlCl3=133,5.0,1=13,35(g)
mFeCl2=127.0,1=12,7(g)
mHCl dư=36,5.0,3=10,95(g)
mdd X=8,3+200-0,25.2=207,8(g)
C% dd AlCl3=\(\dfrac{13,35}{207,8}.100\%=6,42\%\)
C% dd FeCl2=\(\dfrac{12,7}{207,8}.100\%=6,1\%\)
C% dd HCl dư=\(\dfrac{10,95}{207,8}.100\%=5,27\%\)