Dài a, rộng b=> PT(1) : 2.(a+b)=280

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Nồng độ mol/lít các ion trong dd A:

\(\left[OH^-\left(dư\right)\right]=0,06\left(M\right)\left(nt\right)\\\left[Cl^-\right]=2.\left[BaCl_2\right]=2.\left(\dfrac{0,015}{0,5}\right)=0,06\left(M\right)\\ \left[Ba^{2+}\right]=0,03+ 0,03=0,06\left(M\right)\)

\(n_{Ba\left(OH\right)_2}=0,3.0,1=0,03\left(mol\right)\\ n_{HCl}=0,2.0,15=0,03\left(mol\right)\\ Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\\ Vì:\dfrac{n_{Ba\left(OH\right)_2\left(đề\right)}}{n_{Ba\left(OH\right)_2\left(PTHH\right)}}=\dfrac{0,03}{1}>\dfrac{n_{HCl\left(đề\right)}}{n_{HCl\left(PTHH\right)}}=\dfrac{0,03}{2}\\ \Rightarrow Ba\left(OH\right)_2dư\\ n_{Ba\left(OH\right)_2\left(p.ứ\right)}=\dfrac{n_{HCl}}{2}=\dfrac{0,03}{2}=0,015\\ n_{Ba\left(OH\right)_2\left(dư\right)}=0,03-0,015=0,015\left(mol\right)\\ \left[OH^-\right]=2.\left[Ba\left(OH\right)_2\left(dư\right)\right]=\dfrac{0,015}{0,3+0,2}=0,03\left(M\right)\\ \Rightarrow pH=14+log\left[OH^-\right]=14+log\left[0,03\right]\approx12,477\)