PTHH: \(C+O_2\xrightarrow[]{t^o}CO_2\)

              a___a______a    (mol)

            \(S+O_2\xrightarrow[]{t^o}SO_2\)

             b___b_______b   (mol)

Ta lập HPT: \(\left\{{}\begin{matrix}12a+32b=10\\a+b=\dfrac{11,2}{22,4}=0,5\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,3\\b=0,2\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_C=0,3\cdot12=3,6\left(g\right)\\m_S=6,4\left(g\right)\\V_{khí}=0,5\cdot22,4=11,2\left(l\right)\end{matrix}\right.\)

a, \(C+O_2\underrightarrow{t^o}CO_2\)

\(S+O_2\underrightarrow{t^o}SO_2\)

b, Ta có: 12n_C + 32n_S = 2,8 (1)

Theo PT: \(n_{O_2}=n_C+n_S=\dfrac{3,36}{22,4}=0,15\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_C=0,1\left(mol\right)\\n_S=0,05\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_C=\dfrac{0,1.12}{2,8}.100\%\approx42,86\%\\\%m_S\approx57,14\%\end{matrix}\right.\)

Lượng khí hidro thoát ra là 0,15 mol.

a) Al₂O₃ + 2NaOH \(\rightarrow\) 2NaAlO₂ + H₂O

2Al + 2NaOH + 2H₂O \(\rightarrow\) 2NaAlO₂ + 3H₂.

b) Lượng Al phản ứng bằng 2/3 số mol khí hidro thoát ra và bằng 0,1 mol.

\(\Rightarrow\) %m_nhôm=\(\dfrac{27.0,1}{12,9}\).100%\(\approx\)20,93%, %m_{nhôm oxit}\(\approx\)100%-20,93%\(\approx\)79,07%.

Đặt \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)

Theo đề: \(m_{hh}=36\left(g\right)\)

\(\Rightarrow m_{Mg}+m_{Fe}=36\\ \Rightarrow24x+56y=36\left(1\right)\)

\(PTHH:2Mg+O_2\underrightarrow{t^o}2MgO\\ \left(mol\right)....x\rightarrow...0,5x.....x\\ PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\\ \left(mol\right)....y\rightarrow...\dfrac{2}{3}y....\dfrac{1}{3}y\)

Theo đề: \(n_{O_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

\(\Rightarrow0,5x+\dfrac{2}{3}y=0,6\left(2\right)\)

\(\xrightarrow[\left(2\right)]{\left(1\right)}\left\{{}\begin{matrix}24x+56y=36\\0,5x+\dfrac{2}{3}y=0,6\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}x=0,8\\y=0,3\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}m_{Mg}=0,8.24=19,2\left(g\right)\\m_{Fe}=0,3.56=16,8\left(g\right)\end{matrix}\right.\\ m_r=m_{MgO}+m_{Fe_3O_4}=0,8.40+\dfrac{1}{3}.0,3.232=55,2\left(g\right)\)

PTHH: 

mS=10−3,6=6,4(g)⇔nS=6,432=0,2(mol)mS=10−3,6=6,4(g)⇔nS=6,432=0,2(mol)

VO2=(0,3+0,2)22,4=11,2(l)VO2=(0,3+0,2)22,4=11,2(l)

mhh=mCO2+mSO2=0,3.44+0,2.64=26(g)

Đặt \(\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)

Theo đề: \(m_{hh}=39\left(g\right)\)

\(\Rightarrow m_{Al}+m_{Fe}=39\\ \Rightarrow27x+56y=39\left(1\right)\)

\(PTHH:4Al+3O_2\underrightarrow{t^o}2Al_2O_3\\ \left(mol\right)....x\rightarrow..0.75x....0,5x\\ PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\\ \left(mol\right)....y\rightarrow..\dfrac{2}{3}y.....\dfrac{1}{3}y\)

Theo đề: \(n_{O_2}=\dfrac{V}{22,4}=\dfrac{12,32}{22,4}=0,55\left(mol\right)\)

\(\Rightarrow0,75x+\dfrac{2}{3}y=0,55\left(2\right)\)

\(\xrightarrow[\left(1\right)]{\left(2\right)}\left\{{}\begin{matrix}27x+56y=39\\0,75x+\dfrac{2}{3}y=0,55\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,6\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}m_{Al}=0,2.27=5,4\left(g\right)\\m_{Fe}=0,6.56=33,6\left(g\right)\end{matrix}\right.\\ m_r=m_{Al_2O_3}+m_{Fe_3O_4}=0,5.0,2.102+\dfrac{1}{3}.0,6.232=56,6\left(g\right)\)