2Al+6HCl-2AlCl3+3H2

0,5-------------0,5-----0,75

nAl=0,5 mol

m muối=0,5.133,5=66,75 g

VH2=0,75.22,4=16,8g

2

C% = 5/50 .100=10%

n Zn= 19,5/65=0,3 (mol).

PTPƯ: Zn(0.3) +   HCl(0.6) ---->  ZnCl2(0.3) + H2(0,3)

mHCl=0,6.36.5=21.9(g)

a) C%HCl= 21.9/300.100%=7,3%

b) VH2=0,3.22,4=6,72(lít)

c) mH2=0,3.2=0,6(g)

mZnCl2=0,3.136=40,8(g)

mddZnCl2 =(19,5+300)-0,6=318,9(g)

C%=mZnCl2/mddZnCl2.100= 40,8/318,9.100=12,793%

\(a.n_{Mg\left(OH\right)_2}=\dfrac{17,4}{58}=0,3\left(mol\right)\\ Mg\left(OH\right)_2+2HCl\rightarrow MgCl_2+2H_2O\\ n_{HCl}=2n_{Mg\left(OH\right)_2}=0,6\left(mol\right)\\ CM_{HCl}=\dfrac{0,6}{0,2}=3M\\b. n_{Mg\left(OH\right)_2}=n_{MgCl_2}=0,3\left(mol\right)\\ m_{MgCl_2}=0,3.85=25,5\left(g\right)\\c.CM_{MgCl_2}=\dfrac{0,3}{0,2}=1,5M \)

a) $Zn + 2HCl \to ZnCl_2 + H_2$

b) Theo PTHH : 

$n_{ZnCl_2} = n_{Zn} = \dfrac{6,5}{65} = 0,1(mol)$
$m_{ZnCl_2} = 0,1.136 = 13,6(gam)$

c)

$n_{H_2} = n_{Zn} = 0,1(mol) \Rightarrow V_{H_2} = 0,1.22,4 = 2,24(lít)$

d)

$n_{HCl} = 2n_{Zn} = 0,2(mol) \Rightarrow C_{M_{HCl}} = \dfrac{0,2}{0,5} = 0,4M$

nMg = 4,8 : 24 = 0,2 mol

a) Mg  +  H₂SO₄  →  MgSO₄  +   H₂

Theo tỉ lệ phản ứng => nH₂SO₄ phản ứng = nMgSO₄ = nH₂ = 0,2 mol

=> VH₂ = 0,2.22,4 = 4,48 lít.

b)

mH₂SO₄ phản ứng = 0,2.98 = 19,6 gam

=> C% _H2SO4 = \(\dfrac{19,6}{300}.100\text{%}\) = 6,53%

c) mMgSO₄ = 0,2.120 = 24 gam.

PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)

Ta có: \(\left\{{}\begin{matrix}n_{Al}=\dfrac{4,05}{27}=0,15\left(mol\right)\\n_{H_2SO_4}=\dfrac{294\cdot10\%}{98}=0,3\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,15}{2}< \dfrac{0,3}{3}\) \(\Rightarrow\) Axit còn dư

\(\Rightarrow\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=0,075\left(mol\right)=n_{H_2SO_4\left(dư\right)}\\n_{H_2}=0,225\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,225\cdot22,4=5,04\left(l\right)\\m_{Al_2\left(SO_4\right)_3}=0,075\cdot342=25,65\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,075\cdot98=7,35\left(g\right)\\m_{H_2}=0,225\cdot2=0,45\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{Al}+m_{ddH_2SO_4}-m_{H_2}=297,6\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{Al_2\left(SO_4\right)_3}=\dfrac{25,65}{297,6}\cdot100\%\approx8,62\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{7,35}{297,6}\cdot100\%\approx4,47\%\end{matrix}\right.\)

nNa2CO3 = 10,6 / 106 = 0,1 (mol)

Na2CO3 + 2CH3COOH -> 2CH3COONa + H2O + CO2

0,1               0,2                          0,2                           0,1

mdd CH3COOH = 0,2 * 60 / 5 * 100 = 240 (gam)

CO2 + Ca(OH)2 -> CaCO3 + H2O

0,1                            0,1

mCaCO3 = 0,1 * 100 = 10 (gam)

mdd = 240 + 10,6 - 0,1 * 44 = 246,2 (gam)

C% = 82 * 0,2 / 246,2 * 100% = 6,66%

a.\(n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1mol\)

\(Na_2CO_3+2CH_3COOH\rightarrow2CH_3COONa+CO_2+H_2O\)

    0,1                 0,2                       0,2                 0,1                ( mol )

\(m_{ddCH_3COOH}=\dfrac{0,2.60}{5\%}=240g\)

b.\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)

                      0,1          0,1                 ( mol )

\(m_{CaCO_3}=0,1.100=10g\)

c.\(m_{ddspư}=10,6+240-0,1.44=246,2g\)

\(m_{CH_3COONa}=0,2.82=16,4g\)

\(C\%_{CH_3COONa}=\dfrac{16,4}{246,2}.100=6,66\%\)

\(n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1\left(mol\right)\)

PTHH: 

Na₂CO₃ + 2CH₃COOH ---> 2CH₃COONa + CO₂ + H₂O

0,1---------->0,2----------------->0,2--------------->0,1

CO₂ + Ca(OH)₂ ---> CaCO₃ + H₂O

0,1------------------------->0,1

=> \(\left\{{}\begin{matrix}m_{ddCH_3COOH}=\dfrac{0,2.60}{5\%}=240\left(g\right)\\m_{CaCO_3}=0,1.100=10\left(g\right)\end{matrix}\right.\)

\(m_{dd}=10,6+240-0,1.44=246,2\left(g\right)\\ C\%_{CH_3COONa}=\dfrac{82.0,2}{246,2}.100\%=6,66\%\)

\(n_{Zn}=\dfrac{13}{65}=0,2mol\)

\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)

0,2     0,2            0,2           0,2

a)\(V_{H_2}=0,2\cdot22,4=4,48l\)

b)\(m_{ZnSO_4}=0,2\cdot161=32,2g\)

  \(m_{ddZnSO_4}=30+200-0,2\cdot2=229,6g\)

  \(C\%=\dfrac{m_{ct}}{m_{dd}}\cdot100\%=\dfrac{32,2}{229,6}\cdot100\%=14,02\%\)

c)\(n_{CuO}=\dfrac{24}{80}=0,3mol\)

   \(CuO+H_2\rightarrow Cu+H_2O\)

   0,3        0,2     0,2

   \(m_{rắn}=m_{Cu}=0,2\cdot64=12,8g\)

C%=mctmdd⋅100%=19,6200⋅100%=9,8%C%=mctmdd⋅100%=19,6200⋅100%=9,8%

c)

bn mik hỏi tí aj
đoạn mdd ZnSO4 ấy, 30 ở đâu ra v ạ

\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ a.Mg+2HCl\rightarrow MgCl_2+H_2\\ n_{H_2}=n_{MgCl_2}=n_{Mg}=0,2\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\\ b.n_{HCl}=0,2.2=0,4\left(mol\right)\\ m_{ddHCl}=\dfrac{0,4.36,5.100}{7,3}=200\left(g\right)\\ c.m_{ddsau}=4,8+200-0,2.2=204,4\left(g\right)\\ C\%_{ddMgCl_2}=\dfrac{0,2.95}{204,4}.100\approx9,295\%\\ d.V_{ddHCl}=\dfrac{200}{1,05}=\dfrac{4000}{21}\left(ml\right)=\dfrac{4}{21}\left(l\right)\\ C_{MddHCl}=\dfrac{0,4}{\dfrac{4}{21}}=2,1\left(M\right)\)