\(Đặt:n_{Na_2CO_3}=a\left(mol\right);n_{K_2CO_3}=b\left(mol\right)\\ Na_2CO_3+2HCl\rightarrow2NaCl+CO_2+H_2O\\ K_2CO_3+2HCl\rightarrow2KCl+CO_2+H_2O\\ CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3\downarrow+H_2O\\ n_{CaCO_3}=n_{CO_2}=0,3\left(mol\right)\\ \Rightarrow\left\{{}\begin{matrix}106a+138b=38,2\\a+b=0,3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,2\end{matrix}\right.\\ a.C\%_{ddHCl}=\dfrac{0,6.36,5}{200}.100=10,95\%\\ b.m_{ddB}=38,2+200-0,3.44=225\left(g\right)\\ C\%_{ddKCl}=\dfrac{74,5.2.0,2}{225}.100\approx13,244\%\\ C\%_{ddNaCl}=\dfrac{58,5.2.0,1}{225}.100=5,2\%\)

trả lời giùm mik vs

a, \(MgCO_3+2HCl\rightarrow MgCl_2+CO_2+H_2O\)

Ta có: \(n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

Theo PT: \(n_{MgCO_3}=n_{CO_2}=0,2\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{MgCO_3}=\dfrac{0,2.84}{64,8}.100\%\approx25,93\%\\\%m_{MgSO_4}\approx74,07\%\end{matrix}\right.\)

b, - Dung dịch C gồm: MgCl₂, MgSO₄ và HCl dư.

Theo PT: \(\left\{{}\begin{matrix}n_{MgCl_2}=n_{CO_2}=0,2\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{CO_2}=0,4\left(mol\right)\end{matrix}\right.\)

Ta có: \(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)

\(\Rightarrow n_{HCl\left(dư\right)}=0,5-0,4=0,1\left(mol\right)\)

\(m_{MgSO_4}=64,8-0,2.84=48\left(g\right)\Rightarrow n_{MgSO_4}=\dfrac{48}{120}=0,4\left(mol\right)\)

Có: m _{dd sau pư} = 64,8 + 100 - 0,2.44 = 156 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{MgCl_2}=\dfrac{0,2.95}{156}.100\%\approx12,18\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,1.36,5}{156}.100\%\approx2,34\%\\C\%_{MgSO_4}=\dfrac{48}{156}.100\%\approx30,77\%\end{matrix}\right.\)

c, PT: \(MgCl_2+2NaOH\rightarrow2NaCl+Mg\left(OH\right)_{2\downarrow}\)

\(HCl+NaOH\rightarrow NaCl+H_2O\)

\(MgSO_4+2NaOH\rightarrow Na_2SO_4+Mg\left(OH\right)_{2\downarrow}\)

\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)

Theo PT: \(n_{MgO}=n_{Mg\left(OH\right)_2}=n_{MgCl_2}+n_{MgSO_4}=0,6\left(mol\right)\)

\(\Rightarrow m_{cr}=m_{MgO}=0,6.40=24\left(g\right)\)

PTHH: \(Na_2O+H_2O\rightarrow2NaOH\)

            \(2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\downarrow\)

            \(Cu\left(OH\right)_2\xrightarrow[]{t^o}CuO+H_2O\)

a) Ta có: \(n_{NaOH}=2n_{Na_2O}=2\cdot\dfrac{6,2}{62}=0,2\left(mol\right)\) \(\Rightarrow C\%_{NaOH}=\dfrac{0,2\cdot40}{6,2+193,8}\cdot100\%=4\%\)

b) Ta có: \(\left\{{}\begin{matrix}n_{NaOH}=0,2\left(mol\right)\\n_{CuSO_4}=\dfrac{200\cdot16\%}{160}=0,2\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,2}{1}\) \(\Rightarrow\) CuSO₄ còn dư, tính theo NaOH

\(\Rightarrow n_{Cu\left(OH\right)_2}=0,1\left(mol\right)=n_{CuO}\) \(\Rightarrow m_{CuO}=0,1\cdot80=8\left(g\right)\)

c) PTHH: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)

Theo PTHH: \(n_{HCl}=2n_{CuO}=0,2\left(mol\right)\) \(\Rightarrow V_{ddHCl}=\dfrac{0,2}{2}=0,1\left(l\right)=100\left(ml\right)\)

a) Na2O +H2O-->2NaOH (1)

2NaOH +CuSO4 -->Na2SO4+ Cu(OH)2 (2)

Cu(OH)2 -t^o-> CuO +H2O (3)

b) mNa2O=8.100/100=8(g)

=>nNa2O=8/62=0,13(mol)

theo(2) :nCu(OH)2=1/2nNaOH=0,065(mol)

theo(3):nCuO=nCu(OH)2=0,065(mol)

=>mCuO=0,065.80=5,2(g)

c) CuO +2HCl-->CuCl2+H2O (4)

theo (4) : nHCl=2nCuO=0,13(mol)

mddHCl 25%=

MgO+H₂SO₄ → MgSO₄+H₂O(1)

MgCO₃+H₂SO₄ → MgSO₄+ CO₂+H₂O (2)

\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

Theo PT (2): n_MgCO3=n_CO2=0,1mol

=> m_MgCO3=0,1.84=8,4g

m_MgO=16,4-8,4=8g

=> n_MgO=\(\dfrac{8}{40}\) = 0,2mol

Theo PT (1,2) ta có:n_MgSO4=n_MgO+n_MgCO3=0,1+0,2=0,3 mol

n_Ba(OH)2=0,3.1,5 = 0,45 mol

Gọi x là số mol H₂SO₄ còn dư sau phản ứng (1,2).

H₂SO₄+Ba(OH)₂→BaSO₄↓+2H₂O(3)

MgSO₄+Ba(OH)₂→BaSO₄↓+Mg(OH)₂↓(4)

Kết tủa tạo thành gồm BaSO₄ và Mg(OH)₂

Do đó dd B thu được là Ba(OH)₂ dư

Ta có: 233x + 233.0,3 + 58.0,3 =110,6

=>x=0,1mol

Theo PT (3,4): n_{Ba(OH)2 pứ}=n_H2SO4+n_MgSO4=0,1+0,3=0,4mol

n_Ba(OH)2(dư)=0,45−0,4=0,05mol

CM_Ba(OH)2=\(\dfrac{0,05}{0,5}\)=0,1M