n_H2= \(\dfrac{0,896}{22,4}\) = 0,04(mol)

Mg + 2HCl  \(\rightarrow\) MgCl₂  + H₂\(\uparrow\)

a                                  \(\rightarrow\)    a     (mol)

2Al + 6HCl \(\rightarrow\) 2AlCl₃ + 3H₂\(\uparrow\)         (ai dạy Al hóa trị II thế =.=)

b                                  \(\rightarrow\) 1,5b   (mol)

Gọi a,b lần lượt là số mol của Mg và Al

Theo đầu bài, ta có:   \(\left\{{}\begin{matrix}24a+27b=0.78\\a+1,5b=0,04\end{matrix}\right.\) \(\Rightarrow\)\(\left\{{}\begin{matrix}a=0,01\\b=0,02\end{matrix}\right.\)

=> m_Mg= 0,01.24 = 0,24(g)

=> m_Al = 0,78 - 0,24 = 0,54(g)

PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\)

\(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

Theo PTHH: \(n_{Mg}=n_{H_2}=0,6\left(mol\right)\)

=> \(m_{Mg}=0,6.24=14,4\left(g\right)\)

=> \(m_{Cu}=50-14,4=35,6\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%Mg=\dfrac{14,4}{50}.100=28,8\%\\\%Cu=\dfrac{35,6}{50}.100=71,2\%\end{matrix}\right.\)

\(n\)_H2 =\(\dfrac{13,44}{22,4}\) =0,6(mol)
PTHH:
Mg +HCl →MgCl₂ + H₂
0,6 mol                 ←0,6 mol
a) \(m\)_Mg =0,6. 24 =14,4(g)
    \(m\)_Cu= 50- 14,4= 35,6(g)
b)\(m\)%_Mg= \(\dfrac{14,4}{50}\).100%= 28,8%
   \(m\)%_Cu=100%- 28,8%= 71,2%
 

\(n_{HCl}=0,3.1=0,3mol\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

0,1        0,3                        0,15  ( mol )

\(m_{Al}=0,1.27=2,7g\)

\(\Rightarrow m_{Al}=9,1.2,7=6,4g\)

\(V_{H_2}=0,15.22,4=3,36l\)

nHCl = 0,3 . 1 = 0,3 (mol)

PTHH: 2Al + 6HCl -> 2AlCl3 + 3H2

Mol: 0,1 <--- 0,3 ---> 0,1 ---> 0,15

mAl = 0,1 . 27 = 2,7 (g(

mCu = 9,1 - 2,7 = 6,4 (g)

VH2 = 0,15 . 22,4 = 3,36 (l)

\(n_{H_2}=\dfrac{1,12}{22,4}=0,05mol\)

\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)

0,05                                     0,05      ( mol )

( Cu không tác dụng với dd axit H₂SO₄ loãng )

\(m_{Mg}=0,05.24=1,2g\)

\(\rightarrow m_{Cu}=8-1,2=6,8g\)

\(\rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{1,2}{8}.200=15\%\\\%m_{Cu}=100\%-15\%=85\%\end{matrix}\right.\)

\(Đặt:\left\{{}\begin{matrix}Fe:x\left(mol\right)\\Zn:y\left(mol\right)\end{matrix}\right.\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ Tacó:\left\{{}\begin{matrix}56x+65y=5,3\\x+y=0,25\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}x=1,2\\y=-0,97\end{matrix}\right.\left(vô\:lí\right)\)

Em xem lại đề nha!

a)

Gọi : \(\left\{{}\begin{matrix}n_{Al}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\end{matrix}\right.\)⇒ 27a + 56b = 1,66(1)

\(2Al + 6HCl \to 2AlCl_3 + 3H_2\\ Fe +2 HCl \to FeCl_2 + H_2\)

Theo PTHH :

\(n_{H_2} = 1,5a + b = \dfrac{1,12}{22,4} = 0,05(2)\)

Từ (1)(2) suy ra a = 0,02 ; b = 0,02

Vậy :

\(\%m_{Al} = \dfrac{0,02.27}{1,66}.100\% = 32,53\%\\ \%m_{Fe} = 100\% - 32,53\% = 67,47\%\)

a)

\(n_{HCl} = 2n_{H_2} = 0,05.2 = 0,1(mol)\\ \Rightarrow C\%_{HCl} = \dfrac{0,1.36,5}{100}.100\% = 3,65\%\)

\(n_{Zn} = a(mol) ; n_{Al} = b(mol) ; n_{Mg} = c(mol)\\ \Rightarrow 65a + 27b + 24c = 44,1(1)\\ Zn + 2HCl \to ZnCl_2 + H_2\\ 2Al + 6HCl \to 2AlCl_3 + 3 H_2\\ Mg + 2HCl \to MgCl_2 + H_2\\ n_{H_2} = a + 1,5b + c = \dfrac{31,36}{22,4} = 1,4(2)\\ Mà : 2a = 3b(3)\\ (1)(2)(3) \Rightarrow a = 0,3 ; b = 0,2 ; c = 0,8\\ \%m_{Zn} = \dfrac{0,3.65}{44,1}.100\% = 44,22\%\\ \%m_{Al} = \dfrac{0,2.27}{44,1}.100\% = 12,24\%\)

\(\%m_{Mg} = 100\% -44,22\% -12,24\% = 43,54\%\)

a) Đặt \(\left\{{}\begin{matrix}n_{Mg}=a\left(mol\right)\\n_{Al}=b\left(mol\right)\end{matrix}\right.\) \(\Rightarrow24a+27b=5,1\)  (1)

Ta có: \(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)

Bảo toàn electron: \(2a+3b=0,5\)  (2)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,1\cdot24}{5,1}\cdot100\%\approx47,06\%\\\%m_{Al}=52,94\%\end{matrix}\right.\)

b) Bảo toàn nguyên tố: \(n_{HCl}=2n_{H_2}=0,5\left(mol\right)\)

\(\Rightarrow m_{ddHCl}=\dfrac{0,5\cdot36,5}{7,3\%}=250\left(g\right)\)

\(\Rightarrow V_{HCl}=\dfrac{250}{1,2}\approx208,33\left(ml\right)\)