a, Cho hỗn hợp khí CH₄ và C₂H₄ qua dung dịch Br₂ dư chỉ có C₂H₄ tham gia phản ứng. PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

b, \(n_{Br_2}=\dfrac{m_{Br_2}}{M_{Br_2}}=\dfrac{64}{160}=0,4(mol)\)

Theo PTHH: \(n_{C_2H_4}=n_{Br_2}=0,4(mol)\)

\(V_{C_2H_4}=n_{C_2H_4}.22,4=0,4.22,4=8,96(l)\)

Phần trăm của khí C₂H₄ trong hỗn hợp ban đầu là: \(\%V_{C_2H_4}=\dfrac{V_{C_2H_4}}{V_hh}.100\%=\dfrac{8,96}{11,2}.100\%=80\%\)

Phần trăm của khí CH₄ trong hỗn hợp ban đầu là: 

\(\%V_{CH_4}=100\%-\%V_{C_2H_4}=100\%-80\%=20\%\)

a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

b, \(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\)

\(n_{C_2H_4}=n_{Br_2}=0,1\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,1.22,4}{3,36}.100\%\approx66,67\%\\\%V_{CH_4}\approx33,33\%\end{matrix}\right.\)

a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

b, \(n_{Br_2}=\dfrac{19}{160}=0,11875\left(mol\right)\)

\(n_{C_2H_4}=n_{Br_2}=0,11875\left(mol\right)\)

\(\Rightarrow\%V_{C_2H_4}=\dfrac{0,11875.22,4}{5,6}.100\%=47,5\%\)

\(\%V_{CH_4}=100-47,5=52,5\%\)

1. \(n_{Br_2}=0,4.0,5=0,2\left(mol\right)\)

PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Theo PT: \(n_{C_2H_4}=n_{Br_2}=0,2\left(mol\right)\Rightarrow V_{C_2H_4}=0,2.22,4=4,48\left(l\right)\)

2. \(n_{C_2H_4Br_2}=\dfrac{9,4}{188}=0,05\left(mol\right)\)

PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Theo PT: \(n_{C_2H_4}=n_{C_2H_4Br_2}=0,05\left(mol\right)\)

\(\Rightarrow\%V_{C_2H_4}=\dfrac{0,05.22,4}{1,4}.100\%=80\%\)

\(\Rightarrow\%V_{CH_4}=100-80=20\%\)

ta có :

nBr2=\(\dfrac{16}{160}=0,1mol\)

C2H4+Br2->C2H4Br2

0,1------0,1

=>VC2H4=0,1.22,4=2,24l

=>VCH4=3,36l->n CH4=0,15 mol

->%VC2H4=\(\dfrac{2,24}{5,6}.100\)=40%

=>%VCH4=60%

c)

CH4+2O2-to>CO2+2H2O

0,15---------------0,15

C2H4+3O2--to>2CO2+2H2O

0,1--------------------0,2
=>m CaCO3=0,35.100=35g

\(n_{Br_2}=\dfrac{4}{160}=0,025\left(mol\right);n_{hh}=\dfrac{2,8}{22,4}=0,125\left(mol\right)\)

PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

            0,025<-0,125

\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,025}{0,125}.100\%=20\%\\\%V_{CH_4}=100\%-20\%=80\%\end{matrix}\right.\)

a) Khí thoát ra là CH₄

\(\%V_{CH_4} = \dfrac{6,72}{13,44}.100\% = 50\%\\ \%V_{C_2H_4} = 100\% -50\% = 50\%\\ b)\\ C_2H_4 + Br_2 \to C_2H_4Br_2\\ n_{Br_2} = n_{C_2H_4}= \dfrac{13,44.50\%}{22,4} = 0,3(mol)\\ C_{M_{Br_2}} = \dfrac{0,3}{0,2} = 1,5M\)

a, \(n_{Br_2}=\dfrac{48}{160}=0,3\left(mol\right)\)

PT: \(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)

_____0,15____0,3 (mol)

\(\Rightarrow\%V_{C_2H_2}=\dfrac{0,15.22,4}{11,2}.100\%=30\%\)

\(\Rightarrow\%V_{CH_4}=100-30=70\%\)

b, - Khí thoát ra ngoài là CH₄.

\(V_{CH_4}=11,2.70\%=7,84\left(l\right)\)