Sửa đề: Sau phản ứng thu đc \(2240(cm^3)\) lít khí (đktc)

\(n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ a,PTHH:Zn+2HCl\to ZnCl_2+H_2\\ ZnO+2HCl\to ZnCl_2+H_2O\\ b,n_{Zn}=n_{H_2}=0,1(mol)\\ \Rightarrow m_{Zn}=0,1.65=6,5(g)\\ \Rightarrow \%_{Zn}=\dfrac{6,5}{14,6}.100\%= 44,52\%\\ \Rightarrow \%_{ZnO}=100\%-44,52\%=55,48\%\\ n_{ZnO}=\dfrac{14,6-6,5}{81}=0,1(mol)\\ \Sigma n_{ZnCl_2}=n_{Zn}+n_{ZnO}=0,1+0,1=0,2(mol)\\ \Rightarrow C_{M_{ZnCl_2}}=\dfrac{0,2}{0,2}=1M\)

\(a)n_{HCl}=0,2.1,5=0,3mol\\ CaO+2HCl\rightarrow CaCl_2+H_2O\\ CuO+2HCl\rightarrow CuCl_2+H_2O\\ \Rightarrow\left\{{}\begin{matrix}2n_{CaO}+2n_{CuO}=0,3\\56n_{CaO}+80n_{CuO}=10,8\end{matrix}\right.\\ \Rightarrow n_{CaO}=n_{CaCl_2}=0,05mol;n_{CuO}=n_{CuCl_2}=0,1mol\\ \%m_{CaO}=\dfrac{0,05.56}{10,8}\cdot100=25,93\%\\ \%m_{CuO}=100-25,93=74,07\%\\ b)C_{M_{CaCl_2}}=\dfrac{0,05}{0,2}=0,25M\\ C_{M_{CuCl_2}}=\dfrac{0,1}{0,2}=0,5M\)

\(CaO+2HCl\rightarrow CaCl_2+H_2O\)

x            2x            x           x 

\(CuO+2HCl\rightarrow CuCl_2+H_2O\)

y             2y            y          y 

\(\left\{{}\begin{matrix}56x+80y=10,8\\2x+2y=0,2.1,5=0,3\end{matrix}\right.\)

\(\Rightarrow x=0,05;y=0,1\)

\(a,\%m_{CaO}=0,05.56:10,8.100\%=25,93\left(\%\right)\)

\(\%m_{CuO}=100\%-25,93\%=74,07\%\)

\(b,C_{M\left(CaCl_2\right)}=\dfrac{0,05}{0,2}=0,25\left(M\right)\)

\(C_{M\left(CuCl_2\right)}=\dfrac{0,1}{0,2}=0,5\left(M\right)\)

\(n_{FeO}=a\left(mol\right),n_{CuO}=b\left(mol\right)\)

\(m_{hh}=72a+80b=19.2\left(g\right)\left(1\right)\)

\(FeO+H_2SO_4\rightarrow FeSO_4+H_2O\)

\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

\(n_{H_2SO_4}=a+b=0.25\left(mol\right)\left(2\right)\)

\(\left(1\right),\left(2\right):a=0.1,b=0.15\)

\(m_{FeO}=0.1\cdot72=7.2\left(g\right)\)

\(m_{CuO}=12\left(g\right)\)

\(C_{M_{FeSO_4}}=\dfrac{0.1}{0.25}=0.4\left(M\right)\)

\(C_{M_{CuSO_4}}=\dfrac{0.15}{0.25}=0.6\left(M\right)\)

a) PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

                   a_____2a______a_____a      (mol)

                \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)

                    b_____3b_______b_____\(\dfrac{3}{2}\)b         (mol)

Ta lập HPT: \(\left\{{}\begin{matrix}56a+27b=36,1\\a+\dfrac{3}{2}b=\dfrac{21,28}{22,4}=0,95\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,5\\b=0,3\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,5\cdot56=28\left(g\right)\\m_{Al}=8,1\left(g\right)\end{matrix}\right.\)

b+c) Theo các PTHH: \(\left\{{}\begin{matrix}n_{HCl}=2a+3b=1,9\left(mol\right)\\n_{FeCl_2}=0,5\left(mol\right)\\n_{AlCl_3}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{HCl}}=\dfrac{1,9}{0,2}=9,5\left(M\right)\\C_{M_{FeCl_2}}=\dfrac{0,5}{0,2}=2,5\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\)

a) Gọi $n_{Al} =a (mol) ; n_{Fe} = b(mol) \Rightarrow 27a + 56b = 13(1)$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
$Fe + 2HCl \to FeCl_2 + H_2$
Theo PTHH : $n_{H_2} = 1,5a + b = \dfrac{6,72}{22,4} = 0,3(2)$
Từ (1)(2) suy ra : $a = \dfrac{1}{15} ; b = 0,2$

$\%m_{Al} = \dfrac{ \dfrac{1}{15}.27}{13}.100\% = 13,8\%$

$\%m_{Fe} = 100\% - 13,8\% = 86,2\%$

b) $n_{HCl} = 2n_{H_2} = 0,3.2 = 0,6(mol)$
$\Rightarrow C_{M_{HCl}} = \dfrac{0,6}{0,15} = 4M$

c) $n_{muối} = m_{kim\ loại} + m_{HCl} - m_{H_2} = 13 + 0,6.36,5 - 0,3.2 = 34,3(gam)$

CuO + 2HCl -> CuCl₂ + H₂O (1)

Fe₂O₃ + 6HCl -> 2FeCl₃ + 3H₂O (2)

n_HCl=0,2.3,5=0,7(mol)

Đặt n_CuO=a

n_Fe2O3=b

Ta có hệ:

80a+160b=20

2a+6b=0,7

=>a=0,05;b=0,1

m_CuO=80.0,05=4(g)

m_Fe2O3=20-4=16(g)

Theo PTHH 1 và 2 ta có:

n_CuCl2=n_CuO=0,05(mol)

n_FeCl3=2n_Fe2O3=0,2(mol)

m_CuCl2=135.0,05=6,75(g)

m_FeCl3=162,5.0,2=32,5(g)

m_dd =20+200.1,1=240(g)

C% dd CuCl₂=6,72\240 .100%=2,8125%

C% dd FeCl₃= 32,5\240 .100%=13,54%