PTHH: \(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{Ba\left(OH\right)_2}=0,05\cdot0,5=0,025\left(mol\right)\\n_{HCl}=0,15\cdot0,1=0,015\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,025}{1}>\dfrac{0,015}{2}\) \(\Rightarrow\) Ba(OH)₂ còn dư, dd sau p/ứ có tính kiềm

\(\Rightarrow\left\{{}\begin{matrix}n_{BaCl_2}=0,0075\left(mol\right)\\n_{Ba\left(OH\right)_2\left(dư\right)}=0,0175\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{BaCl_2}}=\dfrac{0,0075}{0,05+0,15}=0,0375\left(M\right)\\C_{M_{Ba\left(OH\right)_2}}=\dfrac{0,0175}{0,2}=0,0875\left(M\right)\end{matrix}\right.\)

\(n_{NaOH}=\dfrac{200.5\%}{100\%.40}=0,25(mol)\\ n_{HCl}=\dfrac{36,5.20\%}{100\%.36,5}=0,2(mol)\\ a,NaOH+HCl\to NaCl+H_2O\)

Vì \(\dfrac{n_{NaOH}}{1}>\dfrac{n_{HCl}}{1}\) nên \(NaOH\) dư

\(b,n_{NaOH(dư)}=0,25-0,2=0,05(mol);n_{NaCl}=0,2(mol)\\ \Rightarrow m_{\text{dd sau p/ứ}}=0,2.58,5+0,05.40=13,7(g)\\ c,m_{NaCl}=0,2.58,5=11,7(g)\\ d,n_{H_2}=0,2(mol)\\ \Rightarrow \begin{cases} C\%_{NaOH}=\dfrac{0,05.40}{36,5+200-0,2.2}.100\%=0,85\%\\ C\%_{NaCl}=\dfrac{11,7}{36,5+200-0,2.2}.100\%=4,96\% \end{cases}\)

\(m_{HCl}=\dfrac{300.7,3\%}{100\%}=21,9g\\ n_{HCl}=\dfrac{21,9}{36,5}=0,6mol\\ HCl+NaOH\rightarrow NaCl+H_2O\left(1\right)\\ n_{NaOH\left(1\right)}=n_{HCl}=0,6mol\\ m_{H_2SO_4}=\dfrac{200.9,8\%}{100\%}=19,6g\\ n_{H_2SO_4}=\dfrac{19,6}{98}=0,2mol\\ H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\left(2\right)\\ n_{NaOH\left(2\right)}=0,2.2=0,4mol\\ n_{NaOH}=0,4+0,6=1mol\\ m_{NaOH}=1.40=40g\\ m_{ddNaOH}=\dfrac{40}{5\%}\cdot100\%=800g\)

\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{H_2}=n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\ a,V_{H_2\left(Đktc\right)}=0,2.22,4=4,48\left(l\right)\\ b,m_{ZnCl_2}=136.0,2=27,2\left(g\right)\\ c,n_{HCl}=0,2.2=0,4\left(mol\right)\\ C\%_{ddHCl}=\dfrac{0,4.36,5}{200}.100\%=7,3\%\)

PTHH: \(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\\n_{H_2SO_4}=\dfrac{200\cdot9,8\%}{98}=0,2\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,2}{3}\) \(\Rightarrow\) Fe₂O₃ còn dư, tính theo axit 

\(\Rightarrow\left\{{}\begin{matrix}n_{Fe_2\left(SO_4\right)_3}=0,1\left(mol\right)\\n_{Fe_2O_3\left(dư\right)}=\dfrac{1}{30}\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe_2\left(SO_4\right)_3}=0,1\cdot400=40\left(g\right)\\m_{Fe_2O_3\left(dư\right)}=\dfrac{1}{30}\cdot160\approx5,3\left(g\right)\end{matrix}\right.\)

\(\Rightarrow C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{40}{16+200-5,3}\cdot100\%\approx18,98\%\)

\(m_{ct}=\dfrac{5.200}{100}=10\left(g\right)\)

\(n_{NaOH}=\dfrac{10}{40}=0,25\left(mol\right)\)

Pt : \(NaOH+HCl\rightarrow NaCl+H_2O|\)

           1             1             1         1

        0,25          0,25        0,25

a) \(n_{HCl}=\dfrac{0,25.1}{1}=0,25\left(mol\right)\)

\(m_{HCl}=0,25.36,5=9,125\left(g\right)\)

\(m_{ddHCl}=\dfrac{9,125.100}{3,65}=250\left(g\right)\)

b) \(n_{NaCl}=\dfrac{0,25.1}{1}=0,25\left(mol\right)\)

⇒ \(m_{NaCl}=0,25.58,5=14,625\left(g\right)\)

\(m_{ddspu}=200+250=450\left(g\right)\)

\(C_{NaCl}=\dfrac{14,625.100}{450}=3,25\)⁰/₀

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a) \(n_{NaOH}=\dfrac{200.5\%}{40}=0,25\left(mol\right)\)

PTHH: NaOH + HCl → NaCl + H₂O

Mol:       0,25      0,25    0,25

\(m_{ddHCl}=\dfrac{0,25.36,5.100}{3,65}=250\left(g\right)\)

b) m_{dd sau pứ} = 200 + 250 = 450 (g)

\(C\%_{ddNaCl}=\dfrac{0,25.58,5.100\%}{450}=3,25\%\)

a) $NaOH + HCl \to NaCl + H_2O$

$n_{HCl} = n_{NaOH} = \dfrac{200.5\%}{40} = 0,25(mol)$

$\Rightarrow n_{HCl} = \dfrac{0,25.36,5}{3,65\%} = 250(gam)$

b)

$m_{dd\ sau\ pư} = 200 + 250 = 450(gam)$
$C\%_{NaCl} = \dfrac{0,25.58,5}{450}.100\% = 3,25\%$

\(m_{NaOH}=\dfrac{200\cdot8}{100}=16\left(g\right)\Rightarrow n_{NaOH}=\dfrac{16}{40}=0,4mol\)

\(NaOH+HCl\rightarrow NaCl+H_2O\)

 0,4           0,4         0,4        0,4

a)\(m_{HCl}=0,4\cdot36,5=14,6\left(g\right)\) 

 \(\Rightarrow m_{ddHCl}=\dfrac{14,6}{7,3}\cdot100=200\left(g\right)\)

b)\(m_{NaCl}=0,4\cdot58,5=23,4\left(g\right)\)

   \(m_{H_2O}=0,4\cdot18=7,2\left(g\right)\)

   \(m_{ddsau}=200+200-7,2=392,8\left(g\right)\)

   \(\Rightarrow C\%=\dfrac{23,4}{392,8}\cdot100=5,96\%\)

c) \(n_{SO_2}=\dfrac{6,72}{22,4}=0,3mol\)

     \(2NaOH+SO_2\rightarrow Na_2SO_4+H_2O\)

         0,4          0,3         0,3              0,3

     \(m_{Na_2SO_4}=0,3\cdot142=42,6\left(g\right)\)

Bài 3 : 

\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)

Pt : \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2|\)

        2            3                   1               3

       0,1       0,15                 0,05       0,15

a) \(n_{H2}=\dfrac{0,1.3}{2}=0,15\left(mol\right)\)

\(m_{H2}=0,15.2=0,3\left(g\right)\)

\(V_{H2\left(dktc\right)}=0,15.22,4=3,36\left(l\right)\)

b) \(n_{H2SO4}=\dfrac{0,1.3}{2}=0,15\left(mol\right)\)

⇒ \(m=0,15.98=14,7\left(g\right)\)

\(C_{ddH2SO4}=\dfrac{14,7.100}{200}=7,35\)⁰/₀

c) \(n_{Al2\left(SO4\right)3}=\dfrac{0,15.1}{3}=0,05\left(mol\right)\)

⇒ \(m_{Al2\left(SO4\right)3}=0,05.342=17,1\left(g\right)\)

\(m_{ddspu}=2,7+200-0,3=302,4\left(g\right)\)

\(C_{Al2\left(SO4\right)3}=\dfrac{17,1.100}{302,4}=5,65\)⁰/₀

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