\(n_{Al}=\dfrac{8,1}{27}=0,3\left(mol\right)\\ 2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ n_{H_2SO_4}=n_{H_2}=\dfrac{3}{2}.0,3=0,45\left(mol\right)\\ n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}.0,3=0,15\left(mol\right)\\ m=m_{ddH_2SO_4}=\dfrac{0,45.98.100}{9,8}=450\left(g\right)\\ a=m_{Al_2\left(SO_4\right)_3}=342.0,15=51,3\left(g\right)\\ V=V_{H_2\left(đktc\right)}=0,45.22,4=10,08\left(l\right)\)

\(n_{H_2SO_4}=0,02.1=0,02mol\\ Cu+2H_2SO_4\rightarrow CuSO_4+SO_2+2H_2O\\ CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ \Rightarrow\left\{{}\begin{matrix}80n_{CuO}+64n_{Cu}=0,8\\n_{CuO}+2n_{Cu}=0,02\end{matrix}\right.\\ \Rightarrow n_{CuO}=n_{CuSO_4\left(1\right)}=\dfrac{1}{300}mol\\ n_{Cu}=n_{CuSO_4\left(2\right)}=\dfrac{1}{120}mol\\ m=m_{CuSO_4}=\left(\dfrac{1}{300}+\dfrac{1}{120}\right)\cdot160=1,86g\)

 Tương tự bài 1, ta có:

m 4 o x i t = m m u o i - m H 2 S O 4 + m H 2 O   s a n   p h a m

m 4 o x i t  = 3,61g

⇒ Chọn C.

Theo định luật bảo toàn khối lượng ta có:

m 3 o x i t + m H 2 S O 4 = m m u ố i + m H 2 O   s a n   p h a m

⇔ m m u ố i = m 3 o x i t + m H 2 S O 4 - m H 2 O   s a n   p h a m

Mà n H 2 O  san pham = n H 2 S O 4  = 1.0,05 = 0,05 mol

⇒ m m u o i  = 2,8 + 0,05.98 - 0,05.18 = 6,8g

⇒ Chọn C.

PT: \(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)

Ta có: \(n_{CH_3COONa}=\dfrac{9,84}{82}=0,12\left(mol\right)\)

Theo PT: \(n_{CH_3COOH}=n_{NaOH}=n_{CH_3COONa}=0,12\left(mol\right)\)

\(\Rightarrow V_{ddCH_3COOH}=\dfrac{0,12}{0,5}=0,24\left(l\right)\)

\(m_{NaOH}=0,12.40=4,8\left(g\right)\Rightarrow m_{ddNaOH}=\dfrac{4,8}{20\%}=24\left(g\right)\)

Z tác dụng với $H_2SO_4$ tạo khí suy ra Z có Al,Cu

$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$
$n_{Al} = \dfrac{2}{3}n_{H_2} = 0,02(mol)$

$m_{Cu} = 2,46 - 0,02.27=1,92(gam)$

$n_{Al(OH)_3} = 0,07(mol) ; n_{HCl} = 0,11(mol)$
NaAlO₂ + HCl + H₂O → Al(OH)₃ + NaCl

a................a........................a...............................(mol)

Al(OH)₃ + 3HCl → AlCl₃ + 3H₂O

a - 0,07......3a-0,21..............................(mol)

Suy ra: a + 3a - 0,21 = 0,11 

Suy ra: a = 0,08

$2Na + 2H_2O \to 2NaOH + H_2$
$Na_2O + H_2O \to 2NaOH$
$2Al + 2NaOH + 2H_2O \to 2NaAlO_2 + 3H_2$

Ta có : $n_{H_2} = 0,5n_{Na} + 1,5n_{NaAlO_2} \Rightarrow n_{Na} = \dfrac{0,135 - 1,5.0,08}{0,5} = 0,03(mol)$

Bảo toàn Na,Al

$n_{Na_2O} = \dfrac{0,08 - 0,03}{2} = 0,025(mol)$
$n_{Al} = 0,08 + 0,02 = 0,1(mol)$

$\%m_{Al} = \dfrac{0,1.27}{0,1.27 + 0,025.62 + 0,03.23 + 1,92}.100\% = 39,36\%$

\(n_{H_2SO_4}=n_{H_2}=a(mol)\\ BTKL:\\ m_{hh}+m_{H_2SO_4}=m_{muối}+m_{H_2}\\ 29+98.a=86,6+2.a\\ \to a=0,6(mol)\\ V_{H_2}=0,6.22,4=13,44(l)\)

Đáp án D