\(n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\\ a)Zn+2HCl\rightarrow ZnCl_2+H_2\)

0,1             0,2          0,1         0,1

\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)

\(b)m_{Zn}=0,1.65=6,5g\\ m_{ZnO}=14,6-6,5=8,1g\\ c)n_{ZnO}=\dfrac{8,1}{81}=0,1mol\\ ZnO+2HCl\rightarrow ZnCl_2+H_2O\)

0,1            0,2

\(m_{ddHCl}=\dfrac{\left(0,2+0,2\right)36,5}{14,6}\cdot100=100g\)

\(n_{H_2}=\dfrac{0.56}{22.4}=0.025\left(mol\right)\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(n_{Al}=\dfrac{2}{3}\cdot0.025=\dfrac{1}{60}\left(mol\right)\)

\(m_{Al}=\dfrac{1}{60}\cdot27=0.45\left(g\right)\)

\(m_{Cu}=25-0.45=24.55\left(g\right)\)

\(\%Cu=\dfrac{24.55}{25}\cdot100\%=98.2\%\)

\(\%Al=100-98.2=1.8\%\)

\(Cu+2H_2SO_{4\left(đ\right)}\rightarrow CuSO_4+SO_2+2H_2O\)

\(2Al+6H_2SO_{4\left(đ\right)}\rightarrow Al_2\left(SO_4\right)_3+3SO_2+6H_2O\)

\(n_{Cu}=\dfrac{24.55}{64}=\dfrac{491}{1280}\left(mol\right)\)

\(V_{SO_2}=\left(\dfrac{1}{60}\cdot\dfrac{3}{2}+\dfrac{491}{1280}\right)\cdot22.4=9.1525\left(l\right)\)

a)

$2Al + 6HCl \to 2AlCl_3 + 3H_2$
b)

$n_{H_2} = \dfrac{0,56}{22,4} = 0,225(mol)$

Theo PTHH : $n_{Al} = \dfrac{2}{3}n_{H_2} = \dfrac{1}{60}(mol)$
$m_{Al} = \dfrac{1}{60}.27 = 0,45(gam)$
$m_{Cu} = 25 - 0,45 = 24,55(gam)$

c)

$\%m_{Al} = \dfrac{0,45}{25}.100\% = 1,8\%$
$\%m_{Cu} = 100\% -1,8\% = 98,2\%$

d)

$Cu + 2H_2SO_4 \to CuSO_4 + SO_2 + 2H_2O$
$2Al + 6H_2SO_4 \to Al_2(SO_4)_3 + 3SO_2 + 6H_2O$

Theo PTHH : 

$n_{SO_2} = n_{Cu} + \dfrac{3}{2}n_{Al} = \dfrac{24,55}{64} + \dfrac{1}{60}.\dfrac{3}{2} = 0,41(mol)$
$V_{SO_2} = 0,41.22,4 = 9,184(lít)$

2Al+6HCl->2AlCl3+ 3H2

n(H2)=0,025mol

n(al)= 1/60 mol

m(Al)= 0,45g

m(Cu)= 25-0,45=24,55g

%m(Cu)=98,2%

%m(Al)=1,8%

Cu+2H2SO4(đ)-> CuSO4+SO2+H2O

2Al +6H2SO4(đ)-> Al2(SO4)3 + 3SO2+6H2O

n(so2)=n(Cu)+1,5n(al)= 24,55/64 +1,5*1/60 =523/1280 mol

V(so2)=9,1525lit

a) \(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

PTHH: 2Al + 6HCl → 2AlCl₃ + 3H₂

Mol:       x                                  1,5x

PTHH: Zn + 2HCl → ZnCl₂ + H₂

Mol:       y                                 y

Ta có: \(\left\{{}\begin{matrix}27x+65y=24,9\\1,5x+y=0,6\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}27x+65.\left(0,6-1,5x\right)=24,9\\y=0,6-1,5\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,3\end{matrix}\right.\)

b, \(m_{Al}=0,2.27=5,4\left(g\right);m_{Zn}=24,9-5,4=19,5\left(g\right)\)

c) \(\%m_{Al}=\dfrac{5,4.100\%}{24,9}=21,69\%;\%m_{Zn}=100\%-21,69\%=78,31\%\)

d) 

PTHH: 2Al + 6HCl → 2AlCl₃ + 3H₂

Mol:      0,2     0,6          0,2       0,3

PTHH: Zn + 2HCl → ZnCl₂ + H₂

Mol:      0,3     0,6        0,3       0,3

\(m_{ddHCl}=\dfrac{\left(0,6+0,6\right).36,5.100}{14}=312,857\left(g\right)\)

e) m_{dd sau pứ} = 24,9 + 312,857 - (0,3+0,3).2 = 336,557 (g)

\(C\%_{ddAlCl_3}=\dfrac{0,2.133,5.100\%}{336,557}=7,93\%\)

\(C\%_{ddZnCl_2}=\dfrac{0,3.136.100\%}{336,557}=12,12\%\)

a) $Zn + 2HCl \to ZnCl_2 + H_2$

$ZnO + 2HCl \to ZnCl_2 + H_2O$

b)

Theo PTHH : $n_{Zn} = n_{H_2} = \dfrac{4,48}{22,4} = 0,2(mol)$

$m_{Zn} = 0,2.65 = 13(gam)$

$m_{ZnO} = 21,1 - 13 = 8,1(gam)$

c) $n_{ZnO} = 0,1(mol)$

Theo PTHH : $n_{HCl} = 2n_{Zn} + 2n_{ZnO} = 0,6(mol)$
$m_{dd\ HCl} = \dfrac{0,6.36,5}{16,6\%} = 132(gam)$

d) $m_{dd\ sau\ pư} = 21,1 + 132 - 0,2.2 = 152,7(gam)$
$n_{ZnCl_2} = n_{Zn} + n_{ZnO} = 0,3(mol)$

$C\%_{ZnCl_2} = \dfrac{0,3.136}{152,7}.100\% = 26,72\%$

Trong hỗn hợp Zn và ZnO chỉ có Zn phản ứng với HCl tạo ra 4,48l H2.

nH2 = 4,48/ 22,4 = 0,2 mol

a) Zn + 2HCl ---> ZnCl2 + H2 (1)

   0,2 <-----0,4 <-----0,2 --------0,2

 ZnO + 2HCl ---> ZnCl2 +H2O (2)

0,1------> 0,2 -------> 0,1 -----> 0,1

b) Theo pthh(1) nH2 = nZn = 0,2 mol

=>mZn = 0,2 * 65 = 13g

Khối lượng ZnO trong hỗn hợp ban đầu là 21,1 - mZn = 21,1 - 13= 8,1g => nZnO = 0,1 mol

c) Theo pthh (1),(2), ta có nHCl= 0,4 + 0,2 = 0,6 mol

Khối lượng HCl là : 0.6 * 36,5 = 21,9g

Khối lượng dd HCl là : 21,9 / 16,6% \(\approx131,9\)g

d) Dung dịch sau phản ứng gồm ZnCl2 và nước.

mZnCl2 = (0,1 + 0,2 ) *136 = 40,8g

Theo định luật bảo toàn khối lượng:

Khối lượng dd sau phản ứng thu được là: 21,1 + 131,9 - (0,2 *2) = 152,6g

C%dd = \(\dfrac{40,8}{152,6}\cdot100\%\) = 26,74%

Chúc bạn học tốt!

\(n_{HCl} = \dfrac{448.1,12.3,65\%}{36,5} = 0,50176(mol)\\ Zn + 2HCl \to ZnCl_2 + H_2\\ ZnO + 2HCl \to ZnCl_2 + H_2O\\ n_{Zn} = n_{H_2} = \dfrac{2,24}{22,4} = 0,1(mol)\\ n_{ZnO} = \dfrac{n_{HCl} - 2n_{Zn}}{2} = \dfrac{0,50176-0,1.2}{2} = 0,15088(mol)\\ \%m_{Zn} = \dfrac{0,1.65}{0,1.65 + 0,15088.81}.100\% = 34,72\%\\ \%m_{ZnO} = 65,28\%\)

a) \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(Đặt:n_{Zn}=x\left(mol\right);n_{Fe}=y\left(mol\right)\)

\(n_{H_2}=0,4\left(mol\right)\)

Theo đề ta có hệ \(\left\{{}\begin{matrix}65x+56y=24,2\\x+y=0,4\end{matrix}\right.\)

=> x=0,2 ; y=0,2

\(\%m_{Zn}=\dfrac{0,2.65}{24,2}.100=53,72\%;\%m_{Fe}=46,28\%\)

b)Bảo toàn nguyên tố H: \(n_{HCl}=2n_{H_2}=0,8\left(mol\right)\)

=> \(V_{HCl}=\dfrac{0,8}{2,5}=0,32\left(l\right)\)

c) \(n_{FeCl_2}=0,2\left(mol\right);n_{ZnCl_2}=0,2\left(mol\right)\)

=> \(CM_{FeCl_2}=\dfrac{0,2}{0,32}=0,625\left(mol\right)\)

\(CM_{ZnCl_2}=\dfrac{0,2}{0,32}=0,625\left(mol\right)\)

Đặt: \(\left\{{}\begin{matrix}x=n_{Fe}\left(mol\right)\\y=n_{Al}\left(mol\right)\end{matrix}\right.\)

\(\sum m_{hh}=11\left(g\right)\Rightarrow56x+27y=11\left(1\right)\)

\(PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\\ \left(mol\right)....x\rightarrow..2x........x......x\\ PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\\ \left(mol\right)....y\rightarrow..3y.........y......1,5y\)

\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ \Rightarrow x+1,5y=0,4\left(2\right)\)

\(\xrightarrow[\left(2\right)]{\left(1\right)}\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)

a) \(\%m_{Fe}=\dfrac{56.0,1}{11}=51\%\)

\(\rightarrow\%m_{Al}=49\%\)

b) \(\sum m_{ctHCl}=\left(2.0,1+3.0,2\right).36,5=29,2\left(g\right)\)

\(m_{ddHCl}=\dfrac{29,2.100\%}{10\%}=292\left(g\right)\)

c) \(m_{H_2\uparrow}=\left(1.0,1+1,5.0,2\right).2=0,8\left(g\right)\)

\(m_{ddsaupu}=m_{hh}+m_{ddHCl}-m_{H_2\uparrow}=11+292-0,8=302,2\left(g\right)\)

\(C\%_{FeCl_2}=\dfrac{0,1.127}{302,2}.100=4,2\%\\ C\%_{AlCl_3}=\dfrac{0,2.133,5}{302,2}.100=8,8\%\)

Đặt: {x=nFe(mol)y=nAl(mol){x=nFe(mol)y=nAl(mol)

∑mhh=11(g)⇒56x+27y=11(1)∑mhh=11(g)⇒56x+27y=11(1)

%mFe=56.0,111=51%%mFe=56.0,111=51%

→%mAl=49%→%mAl=49%

b) ∑mctHCl=(2.0,1+3.0,2).36,5=29,2(g)∑mctHCl=(2.0,1+3.0,2).36,5=29,2(g)