Bài 1:
PTHH: \(SO_2+Ba\left(OH\right)_2\rightarrow BaSO_3+H_2O\)
Ta có: \(n_{BaSO_3}=\frac{8,68}{217}=0,04\left(mol\right)\)
\(\Rightarrow n_{SO_2}=0,04mol\) \(\Rightarrow V_{SO_2}=0,04\cdot22,4=0,896\left(l\right)\)
Bài 2:
Ta có: \(\left\{{}\begin{matrix}n_{CO_2}=\frac{5,6}{22,4}=0,25\left(mol\right)\\n_{NaOH}=0,4\cdot1=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Tạo cả 2 muối
PTHH: \(4NaOH+3CO_2\rightarrow Na_2CO_3+2NaHCO_3+H_2O\)
Xét tỉ lệ: \(\frac{0,4}{4}>\frac{0,25}{3}\) \(\Rightarrow\) NaOH dư, CO2 phản ứng hết
\(\Rightarrow\left\{{}\begin{matrix}n_{Na_2CO_3}=\frac{1}{12}\left(mol\right)\\n_{NaHCO_3}=\frac{1}{6}\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{Na_2CO_3}}=\frac{\frac{1}{12}}{6}\approx0,014\left(M\right)\\C_{M_{NaHCO_3}}=\frac{\frac{1}{6}}{6}\approx0,028\left(M\right)\end{matrix}\right.\)