nAL=54:27=2 mol

nAL2O3=1mol

PTHH: 4Al+3O2=>2Al2O3

               2                  1

              2->3/2<==3/2

=> mO2=1,5.32=48g

=> V O2=1,5.22,4=33,6l   

\(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\\ a,3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\\ b,n_{O_2}=\dfrac{2}{3}.0,3=0,2\left(mol\right)\\ \Rightarrow V_{O_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\\ c,n_{Fe_3O_4}=\dfrac{0,3}{3}=0,1\left(mol\right)\\ \Rightarrow m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)

a) PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)

                \(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)

b) Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)=n_{Zn}\) \(\Rightarrow n_{ZnO}=\dfrac{20-0,1\cdot65}{81}=\dfrac{1}{6}\left(mol\right)\)

\(\Rightarrow n_{ZnCl_2}=n_{Zn}+n_{ZnO}=\dfrac{4}{15}\left(mol\right)\) 

Mặt khác: \(m_{H_2}=0,1\cdot2=0,2\left(g\right)\)

\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{H_2}=119,8\left(g\right)\) \(\Rightarrow C\%_{ZnCl_2}=\dfrac{\dfrac{4}{15}\cdot136}{119,8}\cdot100\%\approx30,27\%\)

c) Giả sử khí là SO₂

PTHH: \(Zn+H_2SO_{4\left(đ\right)}\xrightarrow[]{t^o}ZnSO_4+SO_2\uparrow+H_2O\)

Theo PTHH: \(n_{SO_2}=n_{Zn}=0,1\left(mol\right)\) \(\Rightarrow V_{SO_2}=0,1\cdot22,4=2,24\left(l\right)\)

a. \(n_{Al}=\dfrac{27}{27}=1\left(mol\right)\)

\(n_{Al_2O_3}=\dfrac{40.8}{102}=0,4\left(mol\right)\)

PTHH : 4Al + 3O₂ -----t^o---> 2Al₂O₃

              0,8     0,6                   0,4

Xét tỉ lệ : 1 > 0,4 => Al dư , Al₂O₃ đủ

\(m_{Al}=0,8.27=21,6\left(g\right)\)

b. \(m_{tạp.chất}=27-21,6=5,4\left(g\right)\)

\(\%_{tạp.chất}=\dfrac{5.4}{27}.100\%=20\%\)

\(a,PTHH:2ZnS+3O_2\underrightarrow{t^O}2ZnO+2SO_2\) 
\(n_{ZnS}=\dfrac{19,4}{97}=0,2\left(mol\right)\\ n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\) 
\(pthh:2ZnS+3O_2\underrightarrow{t^O}2ZnO+2SO_2\) 
LTL:\(\dfrac{0,2}{2}< \dfrac{0,4}{3}\) 
=> O₂ dư  
theo pthh: \(n_{SO_2}=n_{ZnO}=n_{Zn}=0,2\left(mol\right)\) 
\(m_A=m_{ZnO}=0,2.81=16,2\left(g\right)\) 
Khí B gồm 1 nguyên tử S và 2 nguyên tử O 
dB/kk = \(\dfrac{64}{29}\)

nKClO3 = 4,9/122,5 = 0,04 (mol)

PTHH: 2KClO3 -> (t°, MnO2) 2KCl + 3O2

Mol: 0,04 ---> 0,04 ---> 0,06

mKCl = 0,04 . 74,5 = 2,98 (g)

VO2 = 0,06 . 22,4 = 1,344 (l)

4Na + O2 -> (t°) 2Na2O

0,24 <--- 0,06

mNa = 0,24 . 23 = 5,52 (g)

\(n_{Fe}=\dfrac{1,68}{56}=0,03\left(mol\right)\)

\(3Fe+2O_2\rightarrow\left(t^o\right)Fe_3O_4\)

 0,03   0,02               0,01  ( mol )

\(m_{Fe_3O_4}=0,01.232=2,32\left(g\right)\)

\(V_{kk}=0,02.22,4.5=2,24\left(l\right)\)

\(2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\)

   \(\dfrac{1}{75}\)                               0,02   ( mol )

\(m_{KClO_3}=\dfrac{1}{75}.122,5=1,63\left(g\right)\)

a,nFe=1,68/56=0,03 mol

Ta có PTHH : 3Fe + 2O2 --> Fe3O4 (1) ( ở trên dấu --> có to nha )

Theo PTHH ta có :

nFe3O4=1/3nFe=1/3.0,03=0,01 mol

nO2=2/3nFe=2/3.0,03=0,02 mol

=>mFe3O4= 0,01.232=2,32g

=>Vkk=5.(0,02.22,4)=2,24 l

b, Ta có PTHH: 2KClO3 --> 2KCl + 3O2 (2) ( trên dấu --> vẫn có to )

Gọi x là số mol KClO3 cần dùng ( x > 0 )

Theo PTHH (3) và theo bài ra ta có PTHH sau:

2/3x=0,02 

=> x=0,03 mol

=> mKClO3= 0,03.122,5= 3,675g