a) 2Al + 6HCl -> 2AlCl3 + 3H2

Al2O3 + 6HCl -> 2AlCl3 + 3H2O

nH2 = 0,15mol => nAl=0,1mol => mAl=2,7g; mAl2O3 = 10,2g => nAl2O3 = 0,1mol

=>%mAl=20,93% =>%mAl2O3 = 79,07%

b) nHCl = 0,1.3+0,1.6=0,9 mol=>mHCl(dd)=100g

mddY=12,9+100-0,15.2=112,6g

mAlCl3=22,5g=>C%=19,98%

PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)  (1)

             \(MgO+2HCl\rightarrow MgCl_2+H_2O\)  (2)

a) Ta có: \(n_{H_2}=\dfrac{22,4}{22,4}=1\left(mol\right)=n_{Mg}\) \(\Rightarrow m_{Mg}=1\cdot24=24\left(g\right)\)

\(\Rightarrow\%m_{Mg}=\dfrac{24}{32}\cdot100\%=75\%\) \(\Rightarrow\%m_{MgO}=25\%\)

b) Theo 2 PTHH: \(\left\{{}\begin{matrix}n_{HCl\left(1\right)}=2n_{Mg}=2mol\\n_{HCl\left(2\right)}=2n_{MgO}=2\cdot\dfrac{32-24}{40}=0,4mol\end{matrix}\right.\)

\(\Rightarrow\Sigma n_{HCl}=2,4mol\) \(\Rightarrow m_{ddHCl}=\dfrac{2,4\cdot36,5}{7,3\%}=1200\left(g\right)\)

c) Theo PTHH: \(\Sigma n_{MgCl_2}=\dfrac{1}{2}\Sigma n_{HCl}=1,2mol\)

\(\Rightarrow\Sigma m_{MgCl_2}=1,2\cdot95=114\left(g\right)\)

Mặt khác: \(m_{H_2}=1\cdot2=2\left(g\right)\)

\(\Rightarrow m_{dd}=m_{hh}+m_{ddHCl}-m_{H_2}=1230\left(g\right)\)

\(\Rightarrow C\%_{MgCl_2}=\dfrac{114}{1230}\cdot100\%\approx9,27\%\)

a) Gọi $n_{Al} =a (mol) ; n_{Fe} = b(mol) \Rightarrow 27a + 56b = 13(1)$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
$Fe + 2HCl \to FeCl_2 + H_2$
Theo PTHH : $n_{H_2} = 1,5a + b = \dfrac{6,72}{22,4} = 0,3(2)$
Từ (1)(2) suy ra : $a = \dfrac{1}{15} ; b = 0,2$

$\%m_{Al} = \dfrac{ \dfrac{1}{15}.27}{13}.100\% = 13,8\%$

$\%m_{Fe} = 100\% - 13,8\% = 86,2\%$

b) $n_{HCl} = 2n_{H_2} = 0,3.2 = 0,6(mol)$
$\Rightarrow C_{M_{HCl}} = \dfrac{0,6}{0,15} = 4M$

c) $n_{muối} = m_{kim\ loại} + m_{HCl} - m_{H_2} = 13 + 0,6.36,5 - 0,3.2 = 34,3(gam)$

Đáp án cần chọn là: D