nCl2 = 0,15 mol, nNaBr = 0,15 mol, nNaI = 0,2 mol

Cl2 + 2NaBr -> 2NaCl + Br2

0,075--0,15-----0,15----------

Cl2 + 2NaI -> 2NaCl + I2

0,075--0,15----0,15--------

Dung dịch sau phản ứng có muối NaCl 0,3 mol, NaI 0,2 - 0,15 = 0,05 mol

CM NaCl = 0,3/0,1 = 3M

CM NaI = 0,05/0,1 = 0,5M

\(n_{NaOH}=0.2\cdot0.5=0.1\left(mol\right)\)

\(n_{CuSO_4}=0.1\cdot2=0.2\left(mol\right)\)

\(2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\)

\(0.1.............0.05...............0.05...........0.05\)

\(m_{Cu\left(OH\right)_2}=0.05\cdot98=4.9\left(g\right)\)

\(C_{M_{Na_2SO_4}}=\dfrac{0.05}{0.2+0.1}=0.167\left(M\right)\)

\(C_{M_{CuSO_4\left(dư\right)}}=\dfrac{0.2-0.05}{0.1}=1.5\left(M\right)\)

Ta có: \(n_{MgO}=\dfrac{4}{40}=0,1\left(mol\right)\)

\(n_{HCl}=4.100:1000=0,4\left(mol\right)\)

a. PTHH: MgO + 2HCl ---> MgCl₂ + H₂O

Ta thấy: \(\dfrac{0,1}{1}< \dfrac{0,4}{2}\)

Vậy HCl dư.

=> \(n_{dư}=\dfrac{0,1.2}{0,4}=0,5\left(mol\right)\)

=> \(m_{dư}=0,5.36,5=18,2\left(g\right)\) 

b. Ta có: \(V_{dd_{MgCl_2}}=V_{HCl}=\dfrac{100}{1000}=0,1\left(lít\right)\)

Theo PT: \(n_{MgCl_2}=n_{MgO}=0,1\left(mol\right)\)

=> \(C_{M_{MgCl_2}}=\dfrac{0,1}{0,1}=1M\)

a) $2NaOH + Cl_2 \to NaCl + NaCl + H_2O$

b) $n_{Cl_2} = \dfrac{6,5}{22,4} = 0,29(mol)$

$n_{NaOH} = 2n_{Cl_2} = 0,58(mol)$

$V_{dd\ NaOH} = \dfrac{0,58}{1} = 0,58(lít)$

$n_{NaCl} = n_{NaClO} = n_{Cl_2} = 0,29(mol)$
$C_{M_{NaCl}} = C_{M_{NaClO}} = \dfrac{0,29}{0,58} = 0,5M$

\(n_{HCl}=0,1.1=0,1\left(mol\right)\)

\(n_{Ba\left(OH\right)_2}=0,1.1=0,1\left(mol\right)\)

PTHH :

                 \(2HCl+Ba\left(OH\right)_2\rightarrow BaCl_2+2H_2O\)

trc p/u :        0,1          0,1 

p/u :               0,1       0,05            0,05        0,1

sau p/u :      0            0,05             0,05        0,1 

\(C_{M_{BaCl_2}}=\dfrac{0,05}{0,2}=0,25\left(M\right)\)

\(C_{M_{Ba\left(OH\right)_2dư}}=\dfrac{0,05}{0,2}=0,25\left(M\right)\)

\(m_{BaCl_2}=0,05.208=10,4\left(g\right)\)

2NaOH + CuSO4 → Cu(OH)2 + Na2SO4

n NaOH = 0,2.5 = 1(mol)

n CuSO4 = 0,1.2 = 0,2(mol)

Ta có :

n NaOH / 2 = 0,5 > n CuSO4 / 1 = 0,2 => NaOH dư

n Cu(OH)2 = n CuSO4 = 0,2 mol

=> m A = 0,2.98 = 19,6 gam

n Na2SO4 = n CuSO4 = 0,2 mol

n NaOH pư = 2n CuSO4 = 0,4(mol)

V dd = 0,2 + 0,1 = 0,3(lít)

Suy ra:

CM Na2SO4 = 0,2/0,3 = 0,67M

CM NaOH = (1 - 0,4)/0,3 = 2M

\(a.n_{CO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ a.Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\\ 0,25.......0,25............0,25..........0,25\left(mol\right)\\ C_{MddCa\left(OH\right)_2}=\dfrac{0,25}{0,1}=2,5\left(M\right)\\ b.m_{\downarrow}=m_{CaCO_3}=100.0,25=25\left(g\right)\)

Đáp án D

Z chứa 3 kim loại là Cu, Ag và Fe dư.