nBaCl2=\(\frac{104.10\%}{208}=0,05mol\)

H2SO4 + BaCl2=> BaSO4 + 2HCl

0,05<------0,05----->0,05------>0,1

mdd H2SO4 =\(\frac{0,05.98.100}{7}=70\left(g\right)\)

m tủa = 0,05.233=11,65(g)

mdd = 70+104-11,65=162,35 (g)

C% HCl = \(\frac{0,1.36,5}{162,35}.100\%=2,248\%\)

\(n_{Fe_2O_3}=\dfrac{1,6}{160}=0,01\left(mol\right)\)

\(n_{H_2SO_4}=\dfrac{49.6\%}{98}=0,03\left(mol\right)\)

PTHH:

\(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)

0,01         0,03                0,01   

\(C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{0,01.400}{1,6+49}.100\%=7,91\left(\%\right)\)

c, axit phản ứng hết

Bạn bổ sung thêm số gam dd AgNO₃ nhé.

a)

$K_2SO_4 + BaCl_2 \to BaSO_4 + 2KCl$

b)

$n_{K_2SO_4} = 0,2.2 = 0,4(mol)$
$n_{BaCl_2} = 0,3.1 = 0,3(mol)$

Ta thấy : 

$n_{K_2SO_4} : 1 > n_{BaCl_2} : 1$ nên $K_2SO_4$ dư

$n_{BaSO_4} = n_{BaCl_2} = 0,3(mol)$
$m_{BaSO_4} = 0,3.233 = 69,9(gam)$

c) $n_{K_2SO_4} = 0,4 - 0,3 = 0,1(mol)$

$V_{dd\ sau\ pư} = 0,2 + 0,3 = 0,5(lít)$

$C_{M_{K_2SO_4} } = \dfrac{0,1}{0,5} = 0,2M$
$C_{M_{KCl}} = \dfrac{0,6}{0,5} = 1,2M$

Câu 1:

a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

b, \(n_{Zn}=\dfrac{16,25}{65}=0,25\left(mol\right)\)

\(n_{H_2}=n_{Zn}=0,25\left(mol\right)\)

\(\Rightarrow V_{H_2}=0,25.24,79=6,1975\left(l\right)\)

c, \(n_{HCl}=2n_{Zn}=0,5\left(mol\right)\)

\(\Rightarrow m_{HCl}=0,5.36,5=18,25\left(g\right)\)

\(\Rightarrow m_{ddHCl}=\dfrac{18,25}{10\%}=182,5\left(g\right)\)

d, \(n_{ZnCl_2}=n_{Zn}=0,25\left(mol\right)\)

\(\Rightarrow C\%_{ZnCl_2}=\dfrac{0,25.136}{16,25+182,5-0,25.2}.100\%\approx17,15\%\)

Câu 2:

a, \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)

c, \(n_{NaOH}=\dfrac{40}{40}=1\left(mol\right)\)

Theo PT: \(n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,5\left(mol\right)\)

\(\Rightarrow V_{H_2SO_4}=\dfrac{0,5}{2}=0,25\left(l\right)\)

d, \(n_{Na_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,5\left(mol\right)\)

\(\Rightarrow C_{M_{Na_2SO_4}}=\dfrac{0,5}{0,25}=2\left(M\right)\)

a) PTHH: \(FeCl_3+3NaOH\rightarrow3NaCl+Fe\left(OH\right)_3\downarrow\)

                 \(2Fe\left(OH\right)_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+6H_2O\)

b) Ta có: \(n_{FeCl_3}=0,3\cdot0,5=0,15\left(mol\right)\)

\(\Rightarrow n_{NaOH}=0,45mol\) \(\Rightarrow V_{ddNaOH}=\dfrac{0,45}{0,25}=1,8\left(l\right)\)

c) Theo PTHH: \(n_{NaCl}=n_{NaOH}=0,45mol\)

\(\Rightarrow C_{M_{NaCl}}=\dfrac{0,45}{2,1}\approx0,21\left(M\right)\) 

(Coi như thể tích dd thay đổi không đáng kể)

d) Theo PTHH: \(n_{H_2SO_4}=\dfrac{3}{2}n_{Fe\left(OH\right)_3}=\dfrac{3}{2}n_{FeCl_3}=0,225mol\)

\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,225\cdot98}{20\%}=110,25\left(g\right)\) 

\(\Rightarrow V_{ddH_2SO_4}=\dfrac{110,25}{1,14}\approx96,71\left(ml\right)\)

Gọi \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\)

\(n_{BaSO_4}=\dfrac{11,65}{233}=0,05\left(mol\right)\)

\(Mg+CuSO_4\rightarrow MgSO_4+Cu\)

x------>x--------->x------------>x

\(2Al+3CuSO_4\rightarrow Al_2\left(SO_4\right)_3+3Cu\)

y------>1,5y-------->0,5y-------->1,5y

Có hệ \(\left\{{}\begin{matrix}24x+27y=0,78\\x+1,5y=\dfrac{2,56}{64}\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,01\\y=0,02\end{matrix}\right.\)

Giả sử \(CuSO_4\) phản ứng hết, dung dịch C có: \(\left\{{}\begin{matrix}n_{MgSO_4}=x=0,01\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=0,5y=0,5.0,02=0,01\left(mol\right)\end{matrix}\right.\)

\(MgSO_4+BaCl_2\rightarrow MgCl_2+BaSO_4\) (1)

0,01-------------------------------->0,01

\(Al_2\left(SO_4\right)_3+3BaCl_2\rightarrow3BaSO_4+2AlCl_3\) (2)

0,01------------------------>0,03

Từ PTHH (1), (2) có: \(\Sigma n_{BaSO_4}=0,01+0,03=0,04\left(mol\right)< 0,05\left(mol\right)_{theo.đề}\)

=> Giả sử sai, \(CuSO_4\) dư 

\(CuSO_4+BaCl_2\rightarrow BaSO_4+CuCl_2\)

0,01<-----------------0,01

\(CM_{CuSO_4}=a=\dfrac{x+1,5y+0,01}{0,2}=\dfrac{0,01+1,5.0,02+0,01}{0,2}=0,25\left(M\right)\)

Trong A:

\(n_{Al}=0,02\left(mol\right)\\ n_{Mg}=0,01\left(mol\right)\)