Bài 6:

\(n_{Fe\left(OH\right)_3}=\dfrac{21,4}{107}=0,2\left(mol\right)\)

PT: \(Fe\left(OH\right)_3+3HCl\rightarrow FeCl_3+3H_2O\)

_______0,2________0,6______0,2 (mol)

a, \(C\%_{HCl}=\dfrac{0,6.36,5}{200}.100\%=10,95\%\)

b, \(C\%_{FeCl_3}=\dfrac{0,2.162,5}{21,4+200}.100\%\approx14,68\%\)

Bài 7:

\(m_{H_2SO_4}=100.9,8\%=9,8\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{9,8}{98}=0,1\left(mol\right)\)

PT: \(ZnO+H_2SO_4\rightarrow ZnSO_4+H_2O\)

______0,1______0,1_______0,1 (mol)

a, \(m_{ZnO}=0,1.81=8,1\left(g\right)\)

b, \(C\%_{ZnSO_4}=\dfrac{0,1.161}{8,1+100}.100\%\approx14,89\%\)

Theo gt ta có: $n_{Al}=0,1(mol)$

a, $2Al+6HCl\rightarrow 2AlCl_3+3H_2$

b, $\Rightarrow n_{H_2}=0,15(mol)\Rightarrow V_{H_2}=3,36(l)$

c, Ta có: $n_{HCl}=0,3(mol)\Rightarrow m_{HCl}=10,95(g)\Rightarrow \%m_{ddHCl}=219(g)$

d, Bảo toàn khối lượng ta có: $m_{dd}=221,4(g)$

$\Rightarrow \%C_{AlCl_3}=6,02\%$

PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{Fe}=n_{FeCl_2}=n_{H_2}=0,2\left(mol\right)\\n_{HCl}=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,2\cdot56=11,2\left(g\right)\\m_{FeCl_2}=0,2\cdot127=25,4\left(g\right)\\m_{ddHCl}=\dfrac{0,4\cdot36,5}{10\%}=146\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{Fe}+m_{ddHCl}-m_{H_2}=156,8\left(g\right)\) \(\Rightarrow C\%_{FeCl_2}=\dfrac{25,4}{156,8}\cdot100\%\approx16,2\%\)

a) $n_{Fe} = \dfrac{11,2}{56} = 0,2(mol)$
$Fe + 2HCl \to FeCl_2 + H_2$
$n_{HCl} =2 n_{Fe} = 0,2.2 = 0,4(mol)$
$C\%_{HCl} = \dfrac{0,4.36,5}{200}.100\% = 7,3\%$

b) $n_{H_2} = n_{FeCl_2} = n_{Fe} = 0,2(mol)

Sau phản ứng, $m_{dd} = 11,2 + 200 - 0,2.2 = 210,8(gam)$
$C\%_{FeCl_2} = \dfrac{0,2.127}{210,8}.100\% = 12,05\%$

Fe+2HCl->FeCl₂+H₂

0,125--0,25---0,125-0,125

m _HCl=9,125 g=>n _HCl=\(\dfrac{9,125}{26,5}\)=0,25 mol

=>m Fe=0,125.56=7g

=>V_H2=0,125.22,4=2,8l

=>C%_FeCl2=\(\dfrac{0,125.127}{7+182,5-0,25}\).100=8,388%

\(a) Fe + 2HCl \to FeCl_2\\ b) n_{HCl} = \dfrac{182,5.5\%}{36,5} = 0,25(mol)\\ n_{FeCl_2} = n_{H_2} = n_{Fe} = \dfrac{1}{2}n_{HCl} = 0,125(mol)\\ \Rightarrow m_{Fe} = 0,125.56 = 7(gam) ; V = 0,125.22,4 = 2,8(lít)\\ c) m_{dd\ sau\ phản\ ứng} = m_{Fe} + m_{dd\ HCl} - m_{H_2} = 7 + 182,5 - 0,125.2 = 189,25(gam)\\ C\%_{FeCl_2} = \dfrac{0,125.127}{189,25}.100\% = 8,39\%\)

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