\(n_{Zn}=\dfrac{6.5}{65}=0.1\left(mol\right)\)

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(0.1.....0.2...........0.1..........0.1\)

\(m_{HCl}=0.2\cdot36.5=7.3\left(g\right)\)

\(m_{\text{dung dịch sau phản ứng}}=6.5+146-0.1\cdot2=152.3\left(g\right)\)

\(C\%_{ZnCl_2}=\dfrac{136\cdot0.1}{152.3}\cdot100\%=8.92\%\)

a) $Zn + 2HCl \to ZnCl_2  + H_2$

b)n Zn = 6,5 /65 = 0,1(mol)

n HCl = 2n Zn = 0,2(mol)

m HCl = 0,2.36,5 = 7,3(gam)

c) n H2 = n Zn = 0,1(mol)

m dd = 6,5 + 146 - 0,1.2 = 152,3(gam) 

C% ZnCl2 = 0,1.136/152,3   .100% = 8,93%

Zn + 2HCl --> ZnCl2 + H2

0,5      1              0,5       0,5

nZn=\(\dfrac{32,5}{65}\)=0,5(mol)

mZnCl2=0,5.136=68(g)

VH2=0,5.22,4=11,2(l)

c) CM HCl=\(\dfrac{1}{0,25}=4M\)

a) \(n_{CO_2}=\dfrac{0,4958}{24,79}=0,02\left(mol\right);n_{HCl}=0,6.1=0,6\left(mol\right)\)

PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)

            0,02<------0,04<----0,02<-----0,02

\(\Rightarrow n_{HCl\left(p\text{ư}\right)}< n_{HCl\left(b\text{đ}\right)}\left(0,04< 0,6\right)\Rightarrow HCl\) dư, \(CaCO_3\) tan hết

\(\Rightarrow\left\{{}\begin{matrix}m_{CaCO_3}=0,02.100=2\left(g\right)\\m_{CaSO_4}=5-2=3\left(g\right)\end{matrix}\right.\)

b) dd sau phản ứng có: \(\left\{{}\begin{matrix}n_{HCl\left(d\text{ư}\right)}=0,6-0,04=0,56\left(mol\right)\\n_{CaCl_2}=0,02\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}C_{M\left(HCl\left(d\text{ư}\right)\right)}=\dfrac{0,56}{0,6}=\dfrac{14}{15}M\\C_{M\left(CaCl_2\right)}=\dfrac{0,02}{0,6}=\dfrac{1}{30}M\end{matrix}\right.\)

\(\text{Đặt }n_{Al}=x(mol);n_{Fe}=y(mol)\\ \Rightarrow 27x+56y=13,9(1)\\ n_{H_2}=\dfrac{7,84}{22,4}=0,35(mol)\\ a,PTHH:2Al+6HCl\to 2AlCl_3+3H_2(1)\\ Fe+2HCl\to FeCl_2+H_2(2)\\ b,\text{Từ 2 PT: }1,5x+y=0,35(2)\\ (1)(2)\Rightarrow x=0,1(mol);y=0,2(mol)\\ \Rightarrow m_{Al}=0,1.27=2,7(g)\\ m_{Fe}=0,2.56=11,2(g)\)

\(c,n_{HCl(1)}=3n_{Al}=0,3(mol);n_{AlCl_3}=0,1(mol);n_{H_2(1)}=0,15(mol)\\ \Rightarrow m_{dd_{HCl(1)}}=\dfrac{0,3.36,5}{14,6\%}=75(g)\\ \Rightarrow C\%_{AlCl_3}=\dfrac{0,1.133,5}{2,7+75-0,15.2}.100\%=17,25\%\)

\(n_{HCl(2)}=2n_{Fe}=0,4(mol);n_{FeCl_2}=n_{H_2(2)}=n_{Fe}=0,2(mol)\\ \Rightarrow m{dd_{HCl(2)}}=\dfrac{0,4.36,5}{14,6\%}=100(g)\\ \Rightarrow C\%_{FeCl_2}=\dfrac{0,2.127}{11,2+100-0,2.2}.100\%=22,92\%\)

a) 2Al + 6HCl --> 2AlCl₃ + 3H₂

Fe + 2HCl --> FeCl₂ + H₂

b) Gọi số mol Al, Fe lần lượt là a,b 

=> 27a + 56b = 13,9

\(n_{H_2}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)

2Al + 6HCl --> 2AlCl₃ + 3H₂

a----->3a--------->a------->1,5a______(mol)

Fe + 2HCl --> FeCl₂ + H₂

b------>2b-------->b----->b__________(mol)

=> 1,5a + b = 0,35

=> \(\left\{{}\begin{matrix}a=0,1=>m_{Al}=0,1.27=2,7\left(g\right)\\b=0,2=>m_{Fe}=0,2.56=11,2\left(g\right)\end{matrix}\right.\)

c) n_HCl = 3a + 2b = 0,7 (mol)

=> m_HCl = 0,7.36,5 = 25,55(g)

=> \(m_{ddHCl}=\dfrac{25,55.100}{14,6}=175\left(g\right)\)

\(m_{dd\left(saupu\right)}=13,9+175-2.0,35=188,2\left(g\right)\)

\(\left\{{}\begin{matrix}m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\\m_{FeCl_2}=0,2.127=25,4\left(g\right)\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}C\%\left(AlCl_3\right)=\dfrac{13,35}{188,2}.100\%=7,1\%\\C\%\left(FeCl_2\right)=\dfrac{25,4}{188,2}.100\%=13,5\%\end{matrix}\right.\)

nFe= 16.8/56=0.3 mol

Fe + 2HCl --> FeCl2 + H2

0.3___0.6_____0.3____0.3

VH2=0.2*22.4=6.72l

mFeCl2= 0.3*127=38.1g

CM FeCl2= 0.3/0.6=0.5M

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(n_{Zn}=\dfrac{13}{65}=0,2mol\)

\(m_{HCl}=21,9g\Rightarrow n_{HCl}=\dfrac{21,9}{36,5}=0,6\)

=> HCl dư

\(\Rightarrow n_{H_2}=0,2mol\)

\(\Rightarrow V_{H_2}=0,2.22,4=4,48l\)

bổ sung ý b)

Khối lượng dung dịch sau phản ứng = mZn + mHCl - mH₂ thoát ra = 13 +150 - 0,2 .2 = 162,6 gam

Dung dịch thu được sau phản ứng gồm \(\left\{{}\begin{matrix}ZnCl_2\\HCl_{dư}\end{matrix}\right.\)

nZnCl₂ = nZn = 0,2 mol => mZnCl₂ = 0,2 . 136 = 27,2 gam

=> C% ZnCl₂ = \(\dfrac{27,2}{162,6}\).100= 16,72%

nHCl dư = 0,6 - 0,4 = 0,2 mol 

mHCl dư= 0,2.36,5 = 7,3 gam

=> C% HCl dư = \(\dfrac{7,3}{162,6}\).100 = 4,5%

nAl= 0,5(mol)

a) PTHH: 2 Al + 6 HCl -> 2 AlCl3 + 3 H2

nHCl= 6/2 . 0,5= 1,5(mol)

=>mHCl= 1,5.36,5=54,75(mol)

=> mddHCl= (54,75.100)/18,25=300(g)

b) nH2= 3/2. 0,5=0,75(mol)

=>V(H2,đktc)=0,75.22,4=16,8(l)

c) nAlCl3= nAl= 0,5(mol) -> mAlCl3=0,5. 133,5=66,75(g)

mddAlCl3=mAl+ mddHCl - mH2= 13,5 + 300-0,75.2=312(g)

=> \(C\%ddAlCl3=\dfrac{66,75}{312}.100\approx21,394\%\)