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giúp em vs ạ

Gọi \(\left\{{}\begin{matrix}n_{Zn}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\\n_{Al}=c\left(mol\right)\end{matrix}\right.\) => 65a + 56b + 27c = 10,65 (1)

PTHH: Zn + 2HCl --> ZnCl₂ + H₂

            Fe + 2HCl --> FeCl₂ + H₂

            2Al + 6HCl --> 2AlCl₃ + 3H₂

=> \(n_{H_2}=a+b+1,5c=\dfrac{5,04}{22,4}=0,225\left(mol\right)\) (2)

PTHH: Zn + Cl₂ --t^o--> ZnCl₂

            2Fe + 3Cl₂ --t^o--> 2FeCl₃

            2Al + 3Cl₂ --t^o--> 2AlCl₃

=> \(n_{Cl_2}=a+1,5b+1,5c=\dfrac{5,6}{22,4}=0,25\left(mol\right)\) (3)

(1)(2)(3) => \(\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,05\left(mol\right)\\c=0,05\left(mol\right)\end{matrix}\right.\) => \(\left\{{}\begin{matrix}m_{Zn}=0,1.65=6,5\left(g\right)\\m_{Fe}=0,05.56=2,8\left(g\right)\\m_{Al}=0,05.27=1,35\left(g\right)\end{matrix}\right.\)

a) \(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{6,5}{10,65}.100\%=61,033\%\\\%m_{Fe}=\dfrac{2,8}{10,65}.100\%=26,291\%\\\%m_{Al}=\dfrac{1,35}{10,65}.100\%=12,676\%\end{matrix}\right.\)

b) n_HCl = 2a + 2b + 3c = 0,45 (mol)

=> m_HCl = 0,45.36,5 = 16,425 (g)

=> \(a\%=C\%=\dfrac{16,425}{200}.100\%=8,2125\%\)

c) m_{dd sau pư} = 10,65 + 200 - 0,225.2 = 210,2 (g)

=> \(\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,1.136}{210,2}.100\%=6,47\%\\C\%_{FeCl_2}=\dfrac{0,05.127}{210,2}.100\%=3,02\%\\C\%_{AlCl_3}=\dfrac{0,05.133,5}{210,2}.100\%=3,176\%\end{matrix}\right.\)

\(3Ag+4HNO_3\rightarrow3AgNO_3+NO+2H_2O\)

\(Al+4HNO_3\rightarrow Al\left(NO_3\right)_3+NO+2H_2O\)

\(NO\) là sản phẩm khử duy nhất.

\(\Rightarrow n_{NO}=\dfrac{0,448}{22,4}=0,02mol\)

Ta có: \(\left\{{}\begin{matrix}27n_{Al}+108n_{Ag}=3,51g\\BTe:3n_{Al}+n_{Ag}=3n_{NO}=0,06\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}n_{Al}=0,01mol\\n_{Ag}=0,03mol\end{matrix}\right.\)

\(\%m_{Al}=\dfrac{0,01\cdot27}{3,51}\cdot100\%=7,7\%\)

\(\%m_{Ag}=100\%-7,7\%=92,3\%\)

a, \(Al+4HNO_3\rightarrow Al\left(NO_3\right)_3+NO+2H_2O\)

\(3Ag+4HNO_3\rightarrow3AgNO_3+NO+2H_2O\)

b, \(\left\{{}\begin{matrix}\underrightarrow{BTE}3n_{Al}+n_{Ag}=\dfrac{0,448.3}{22,4}=0,06\\\underrightarrow{BTKL}27n_{Al}+108n_{Ag}=3,51\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}n_{Al}=0,01\\n_{Ag}=0,03\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%Al=\dfrac{0,01.27}{3,51}.100\%=7,69\%\\\%Ag=\dfrac{0,03.108}{3,51}.100\%=92,31\%\end{matrix}\right.\)

Đáp án B

n_Al = 5,4: 27 = 0,2 mol

Bảo toàn electron: 3n_Al = 3n_NO => n_NO = n_Al  = 0,2 mol

=> V_NO = 0,2.22,4 = 4,48 lít

Sửa: $V_{H_2}=7,168(l)$

$a\bigg)$

Đặt $n_{Mg}=x;n_{Fe}=y;n_{Al}=z$

$\to 24x+56y+27z=9,52(1)$

$n_{H_2}=\dfrac{7,168}{22,4}=0,32(mol)$

$n_{Cl_2}=\dfrac{8,064}{22,4}=0,36(mol)$

BTe: $x+y+1,5z=n_{H_2}=0,32(2)$

BTe: $x+1,5y+1,5z=n_{Cl_2}=0,36(3)$

Từ $(1)(2)(3)\to x=0,12(mol);y=0,08(mol);z=0,08(mol)$

$\to \begin{cases} \%m_{Mg}=\dfrac{0,12.24}{9,52}.100\%=30,25\%\\ \%m_{Fe}=\dfrac{0,08.56}{9,52}.100\%=47,06\%\\ \%m_{Al}=100-47,06-30,25=22,69\% \end{cases}$

$b\bigg)$

Bảo toàn H: $n_{HCl}=2n_{H_2}=0,64(mol)$

$\to C_{M_{HCl}}=\dfrac{0,64}{0,2}=3,2M$

$\to a=3,2$

$c\bigg)$

Dung dịch sau gồm $MgCl_2,FeCl_2,AlCl_3$

Bảo toàn $Mg,Al,Fe:n_{MgCl_2}=0,12(mol);n_{AlCl_3}=n_{FeCl_2}=0,08(mol)$

$\to C_{M_{MgCl_2}}=\dfrac{0,12}{0,2}=0,6M$

$\to C_{M_{AlCl_3}}=C_{M_{FeCl_2}}=\dfrac{0,08}{0,2}=0,4M$

$a\bigg)$

Đặt $n_{Mg}=x;n_{Fe}=y;n_{Al}=z$

$\to 24x+56y+27z=9,52(1)$

$n_{H_2}=\dfrac{14,336}{22,4}=0,64(mol)$

$n_{Cl_2}=\dfrac{8,064}{22,4}=0,36(mol)$

BTe: $x+y+1,5z=n_{H_2}=0,64(2)$

BTe: $x+1,5y+1,5z=n_{Cl_2}=0,36(3)$

Từ $(1)(2)(3)\to$ nghiệm âm, xem lại đề